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A Radical Intermediate in the Conversion of Pentachlorophenol to Tetrachlorohydroquinone by Sphingobium chlorophenolicum

[Image: see text] Pentachlorophenol (PCP) hydroxylase, the first enzyme in the pathway for degradation of PCP in Sphingobium chlorophenolicum, is an unusually slow flavin-dependent monooxygenase (k(cat) = 0.02 s(–1)) that converts PCP to a highly reactive product, tetrachlorobenzoquinone (TCBQ). Usi...

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Detalles Bibliográficos
Autores principales:	Rudolph, Johannes, Erbse, Annette H., Behlen, Linda S., Copley, Shelley D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4204890/ https://www.ncbi.nlm.nih.gov/pubmed/25238136 http://dx.doi.org/10.1021/bi5010427

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