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Pd-Catalyzed α-Arylation of Trimethylsilyl Enolates of α,α-Difluoroacetamides
[Image: see text] We report the arylation and heteroarylation of α,α-difluoro-α-(trimethylsilyl)acetamides with aryl and heteroaryl bromides catalyzed by an air- and moisture-stable palladacyclic complex containing P(t-Bu)(2)Cy as ligand. A broad range of electronically varied aryl and heteroaryl br...
Autores principales: | Ge, Shaozhong, Arlow, Sophie I., Mormino, Michael G., Hartwig, John F. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4210146/ https://www.ncbi.nlm.nih.gov/pubmed/25254966 http://dx.doi.org/10.1021/ja508590k |
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