Facile fabrication of sub-100 nm mesoscale inverse opal films and their application in dye-sensitized solar cell electrodes

Inverse opal (IO) films with mesoporous structures hold promise as high-performance electrodes for various photoelectrochemical devices because of their high specific area as well as their fully connected pore structure. A great challenge to their use is obtaining an intact film of mesoscale colloidal crystals as a template. Here, using the plate-sliding coating method coupled with hot air flow, we successfully deposited mesoscale colloidal crystals onto the substrate. A TiO(2) mesoscale IO (meso-IO) with 70 nm pores was then successfully fabricated via atomic layer deposition of TiO(2) and subsequent removal of the template. As a photoelectrochemical electrode, the meso-IO structure exhibits enhanced charge transport properties as well as a high specific area. Moreover, dye-sensitized solar cells fabricated using the meso-IO electrode exhibit a higher photocurrent and cell efficiency than a cell constructed using a conventional TiO(2) nanoparticle electrode. This meso-IO film provides a new platform for developing electrodes for use in various energy storage and conversion devices.