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In-situ X-ray diffraction snapshotting: Determination of the kinetics of a photodimerization within a single crystal

In a single-crystal-to-single-crystal (SCSC) transformation, a preformed three-dimensional coordination polymer,[Ni(3)(oba)(2)(bpe)(2)(SO(4))(H(2)O)(4)]·H(2)O (H(2)oba = 4,4′-oxydibenzoic acid; bpe = (E)-1,2-di(pyridin-4-yl)ethane) (1), was shown to undergo a [2+2] cycloaddition reaction upon exposu...

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Detalles Bibliográficos
Autores principales: Hu, Fei-Long, Wang, Shu-Long, Lang, Jian-Ping, Abrahams, Brendan F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4212243/
https://www.ncbi.nlm.nih.gov/pubmed/25351677
http://dx.doi.org/10.1038/srep06815

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