Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes

A series of bicationic monochromophoric hemicyanine dyes based on benzothiazolestyrylium residues were synthesized. The dyeing photoinitiating systems consisting of N-[3-(4-methylpyridino)propyl]-2-(p-substituted styryl)benzothiazolium dihalides as chromophores and n-butyltriphenylborate anion as el...

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Detalles Bibliográficos
Autores principales: Kabatc, Janina, Jurek, Katarzyna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Berlin Heidelberg 2014
Materias:
Original Contribution
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4223542/
https://www.ncbi.nlm.nih.gov/pubmed/25400318
http://dx.doi.org/10.1007/s00396-014-3343-4
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author Kabatc, Janina
Jurek, Katarzyna
author_facet Kabatc, Janina
Jurek, Katarzyna
author_sort Kabatc, Janina
collection PubMed
description A series of bicationic monochromophoric hemicyanine dyes based on benzothiazolestyrylium residues were synthesized. The dyeing photoinitiating systems consisting of N-[3-(4-methylpyridino)propyl]-2-(p-substituted styryl)benzothiazolium dihalides as chromophores and n-butyltriphenylborate anion as electron donor were also prepared to achieve an efficient photoinitiators for free-radical polymerization in a visible-light region. The relative photoinitiating efficiencies of novel photoinitiators of acrylate monomers polymerization were evaluated.
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spelling pubmed-42235422014-11-12 Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes Kabatc, Janina Jurek, Katarzyna Colloid Polym Sci Original Contribution A series of bicationic monochromophoric hemicyanine dyes based on benzothiazolestyrylium residues were synthesized. The dyeing photoinitiating systems consisting of N-[3-(4-methylpyridino)propyl]-2-(p-substituted styryl)benzothiazolium dihalides as chromophores and n-butyltriphenylborate anion as electron donor were also prepared to achieve an efficient photoinitiators for free-radical polymerization in a visible-light region. The relative photoinitiating efficiencies of novel photoinitiators of acrylate monomers polymerization were evaluated. Springer Berlin Heidelberg 2014-08-14 2014 /pmc/articles/PMC4223542/ /pubmed/25400318 http://dx.doi.org/10.1007/s00396-014-3343-4 Text en © The Author(s) 2014 https://creativecommons.org/licenses/by/4.0/ Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
spellingShingle Original Contribution
Kabatc, Janina
Jurek, Katarzyna
Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
title Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
title_full Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
title_fullStr Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
title_full_unstemmed Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
title_short Visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
title_sort visible light-induced polymerization initiated by borate salts of bicationic monochromophoric benzothiazolestyrylium dyes
topic Original Contribution
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4223542/
https://www.ncbi.nlm.nih.gov/pubmed/25400318
http://dx.doi.org/10.1007/s00396-014-3343-4
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