Cargando…
Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids
[Image: see text] The first asymmetric insertion reactions of donor–donor carbenoids, i.e., those with no pendant electron-withdrawing groups, are reported. This process enables the synthesis of densely substituted benzodihydrofurans with high levels of enantio- and diastereoselectivity. Preliminary...
Autores principales: | Soldi, Cristian, Lamb, Kellan N., Squitieri, Richard A., González-López, Marcos, Di Maso, Michael J., Shaw, Jared T. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227726/ https://www.ncbi.nlm.nih.gov/pubmed/25308822 http://dx.doi.org/10.1021/ja508586t |
Ejemplares similares
-
Enantioselective carbenoid insertion into C(sp(3))–H bonds
por: Santiago, J V, et al.
Publicado: (2016) -
Palladium-catalyzed intramolecular enantioselective C(sp(3))–H insertion of donor/donor carbenes
por: Li, Wendeng, et al.
Publicado: (2022) -
Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes
por: Nickerson, Leslie A., et al.
Publicado: (2019) -
Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes
por: Nickerson, Leslie A., et al.
Publicado: (2020) -
Rh(2)(ii)-catalyzed enantioselective intramolecular Büchner reaction and aromatic substitution of donor–donor carbenes
por: Zhu, Dong, et al.
Publicado: (2022)