Cargando…
Selective Oxidative Homo- and Cross-Coupling of Phenols with Aerobic Catalysts
[Image: see text] Simple catalysts that use atom-economical oxygen as the terminal oxidant to accomplish selective ortho–ortho, ortho–para, or para–para homo-couplings of phenols are described. In addition, chromium salen catalysts have been discovered as uniquely effective in the cross-coupling of...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4227839/ https://www.ncbi.nlm.nih.gov/pubmed/24797179 http://dx.doi.org/10.1021/ja500183z |
| Sumario: | [Image: see text] Simple catalysts that use atom-economical oxygen as the terminal oxidant to accomplish selective ortho–ortho, ortho–para, or para–para homo-couplings of phenols are described. In addition, chromium salen catalysts have been discovered as uniquely effective in the cross-coupling of different phenols with high chemo- and regioselectivity. |
|---|