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Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)

Previous studies investigating manufacture of phosphate-based glass fibres from glasses fixed with P(2)O(5) content less than 50 mol% showed that continuous manufacture without breakage was very difficult. In this study, nine phosphate-based glass formulations from the system P(2)O(5)-CaO-Na(2)O-MgO...

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Autores principales: Sharmin, Nusrat, Parsons, Andrew J, Rudd, Chris D, Ahmed, Ifty
Formato: Online Artículo Texto
Lenguaje:English
Publicado: SAGE Publications 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4230965/
https://www.ncbi.nlm.nih.gov/pubmed/24939962
http://dx.doi.org/10.1177/0885328214539824
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author Sharmin, Nusrat
Parsons, Andrew J
Rudd, Chris D
Ahmed, Ifty
author_facet Sharmin, Nusrat
Parsons, Andrew J
Rudd, Chris D
Ahmed, Ifty
author_sort Sharmin, Nusrat
collection PubMed
description Previous studies investigating manufacture of phosphate-based glass fibres from glasses fixed with P(2)O(5) content less than 50 mol% showed that continuous manufacture without breakage was very difficult. In this study, nine phosphate-based glass formulations from the system P(2)O(5)-CaO-Na(2)O-MgO-B(2)O(3) were prepared with P(2)O(5) contents fixed at 40, 45 and 50 mol%, where Na(2)O was replaced by 5 and 10 mol% B(2)O(3) and MgO and CaO were fixed to 24 and 16 mol%, respectively. The effect of B(2)O(3) addition on the fibre drawing, fibre mechanical properties and dissolution behaviour was investigated. It was found that addition of 5 and 10 mol% B(2)O(3) enabled successful drawing of continuous fibres from glasses with phosphate (P(2)O(5)) contents fixed at 40, 45 and 50 mol%. The mechanical properties of the fibres were found to significantly increase with increasing B(2)O(3) content. The highest tensile strength (1200 ± 130 MPa) was recorded for 45P(2)O(5)-16CaO-5Na(2)O-24MgO-10B(2)O(3) glass fibres. The fibres were annealed, and a comparison of the mechanical properties and mode of degradation of annealed and non-annealed fibres were investigated. A decrease in tensile strength and an increase in tensile modulus were observed for the annealed fibres. An assessment of the change in mechanical properties of both the annealed and non-annealed fibres was performed in phosphate-buffered saline (PBS) at 37℃ for 28 and 60 days, respectively. Initial loss of mechanical properties due to annealing was found to be recovered with degradation. The B(2)O(3)-containing glass fibres were found to degrade at a much slower rate as compared to the non-B(2)O(3)-containing fibres. Both annealed and non-annealed fibres exhibited a peeling effect of the fibre's outer layer during degradation.
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spelling pubmed-42309652014-11-20 Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5) Sharmin, Nusrat Parsons, Andrew J Rudd, Chris D Ahmed, Ifty J Biomater Appl Biomaterials Processing Previous studies investigating manufacture of phosphate-based glass fibres from glasses fixed with P(2)O(5) content less than 50 mol% showed that continuous manufacture without breakage was very difficult. In this study, nine phosphate-based glass formulations from the system P(2)O(5)-CaO-Na(2)O-MgO-B(2)O(3) were prepared with P(2)O(5) contents fixed at 40, 45 and 50 mol%, where Na(2)O was replaced by 5 and 10 mol% B(2)O(3) and MgO and CaO were fixed to 24 and 16 mol%, respectively. The effect of B(2)O(3) addition on the fibre drawing, fibre mechanical properties and dissolution behaviour was investigated. It was found that addition of 5 and 10 mol% B(2)O(3) enabled successful drawing of continuous fibres from glasses with phosphate (P(2)O(5)) contents fixed at 40, 45 and 50 mol%. The mechanical properties of the fibres were found to significantly increase with increasing B(2)O(3) content. The highest tensile strength (1200 ± 130 MPa) was recorded for 45P(2)O(5)-16CaO-5Na(2)O-24MgO-10B(2)O(3) glass fibres. The fibres were annealed, and a comparison of the mechanical properties and mode of degradation of annealed and non-annealed fibres were investigated. A decrease in tensile strength and an increase in tensile modulus were observed for the annealed fibres. An assessment of the change in mechanical properties of both the annealed and non-annealed fibres was performed in phosphate-buffered saline (PBS) at 37℃ for 28 and 60 days, respectively. Initial loss of mechanical properties due to annealing was found to be recovered with degradation. The B(2)O(3)-containing glass fibres were found to degrade at a much slower rate as compared to the non-B(2)O(3)-containing fibres. Both annealed and non-annealed fibres exhibited a peeling effect of the fibre's outer layer during degradation. SAGE Publications 2014-11 /pmc/articles/PMC4230965/ /pubmed/24939962 http://dx.doi.org/10.1177/0885328214539824 Text en © The Author(s) 2014 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav http://creativecommons.org/licenses/by-nc/3.0/ This article is distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 License (http://www.creativecommons.org/licenses/by-nc/3.0/) which permits non-commercial use, reproduction and distribution of the work without further permission provided the original work is attributed as specified on the SAGE and Open Access page(http://www.uk.sagepub.com/aboutus/openaccess.htm).
spellingShingle Biomaterials Processing
Sharmin, Nusrat
Parsons, Andrew J
Rudd, Chris D
Ahmed, Ifty
Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)
title Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)
title_full Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)
title_fullStr Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)
title_full_unstemmed Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)
title_short Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P(2)O(5)
title_sort effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% p(2)o(5)
topic Biomaterials Processing
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4230965/
https://www.ncbi.nlm.nih.gov/pubmed/24939962
http://dx.doi.org/10.1177/0885328214539824
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