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Merging Gold and Organocatalysis: A Facile Asymmetric Synthesis of Annulated Pyrroles
The combination of cinchona-alkaloid-derived primary amine and Au(I)–phosphine catalysts allowed the selective C—H functionalization of two adjacent carbon atoms of pyrroles under mild reaction conditions. This sequential dual activation provides seven-membered-ring-annulated pyrrole derivatives in...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4238261/ https://www.ncbi.nlm.nih.gov/pubmed/24590817 http://dx.doi.org/10.1002/chem.201400407 |