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A catalytic asymmetric total synthesis of (–)-perophoramidine

We report a catalytic asymmetric total synthesis of the ascidian natural product perophoramidine. The synthesis employs a molybdenum-catalyzed asymmetric allylic alkylation of an oxindole nucleophile and a monosubstituted allylic electrophile as a key asymmetric step. The enantioenriched oxindole pr...

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Detalles Bibliográficos
Autores principales:	Trost, B. M., Osipov, M., Krüger, S., Zhang, Y.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4251524/ https://www.ncbi.nlm.nih.gov/pubmed/25485074 http://dx.doi.org/10.1039/c4sc01826e

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