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Crystal structure of 2-pentyloxybenzamide
In the title molecule, C(12)H(17)NO(2), the amide NH(2) group is oriented toward the pentyloxy substituent and an intramolecular N—H⋯O hydrogen bond is formed with the pentyloxy O atom. The benzene ring forms dihedral angles of 2.93 (2) and 5.60 (2)° with the amide group and the pentyloxy group...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257159/ https://www.ncbi.nlm.nih.gov/pubmed/25484660 http://dx.doi.org/10.1107/S1600536814020571 |
Sumario: | In the title molecule, C(12)H(17)NO(2), the amide NH(2) group is oriented toward the pentyloxy substituent and an intramolecular N—H⋯O hydrogen bond is formed with the pentyloxy O atom. The benzene ring forms dihedral angles of 2.93 (2) and 5.60 (2)° with the amide group and the pentyloxy group mean planes, respectively. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with their molecular planes parallel, but at an offset of 0.45 (1) Å to each other. These dimers are ordered into two types of symmetry-related columns extended along the a axis, with the mean plane of one set of dimers in a column approximately parallel to (121) and the other in a column approximately parallel to (1-21). The two planes form a dihedral angle of 85.31 (2)°, and are linked via C—H⋯O hydrogen bonds and C—H⋯π interactions, forming a three-dimensional framework structure. |
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