Crystal structures of trans-acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)(di­methyl­phenyl­phosphane)molybdenum(II) and trans-acetyl­dicarbon­yl(η(5)-cyclo­penta­dien­yl)(ethyl­diphenyl­phosphane)molybdenum(II)

The title compounds, [Mo(C(5)H(5))(COCH(3))P(CH(3))(2)(C(6)H(5))(CO)(2)], (1), and [Mo(C(5)H(5))(COCH(3))P(C(2)H(5))(C(6)H(5))(2))(CO)(2)], (2), have been prepared by phosphine-induced migratory insertion from [Mo(C(5)H(5))(CO)(3)(CH(3))]. Both complex mol­ecules exhibit a four-legged piano-stool ge...

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Detalles Bibliográficos
Autores principales: Whited, Matthew T., Hofmeister, Gretchen E., Hodges, Connor J., Jensen, Laramie T., Keyes, Samuel H., Ngamnithiporn, Aurapat, Janzen, Daron E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257160/
https://www.ncbi.nlm.nih.gov/pubmed/25484656
http://dx.doi.org/10.1107/S1600536814020534

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