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Crystal structure of ethyl 2-[(4-bromo­phen­yl)amino]-3,4-di­methyl­pent-3-enoate

In the title compound, C(15)H(20)BrNO(2), there are two independent mol­ecules (A and B) comprising the asymmetric unit and these adopt very similar conformations. In A, the dihedral angle between the CO(2) and MeC=CMe(2) groups is 80.7 (3)°, and these make dihedral angles of 3.5 (3) and 84.09 (16)°...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Caracelli, I., Stefani, Hélio A., Khan, Amna N., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257164/
https://www.ncbi.nlm.nih.gov/pubmed/25484707
http://dx.doi.org/10.1107/S1600536814020832
Descripción
Sumario:In the title compound, C(15)H(20)BrNO(2), there are two independent mol­ecules (A and B) comprising the asymmetric unit and these adopt very similar conformations. In A, the dihedral angle between the CO(2) and MeC=CMe(2) groups is 80.7 (3)°, and these make dihedral angles of 3.5 (3) and 84.09 (16)°, respectively, with the bromo­benzene ring. The equivalent dihedral angles for mol­ecule B are 78.4 (3), 2.1 (3) and 78.37 (12)°, respectively. The most prominent inter­actions in the crystal packing are amine-N—H⋯O(carbon­yl) hydrogen bonds between the two independent mol­ecules, resulting in non-centrosymmetric ten-membered {⋯OC(2)NH}(2) synthons. Statistical disorder is noted for each of the terminal methyl groups of the ethyl residues.