Cargando…
Crystal structure of 5-chloro-3-(4-fluorophenylsulfinyl)-2,4,6-trimethyl-1-benzofuran
In the title compound, C(17)H(14)ClFO(2)S, the dihedral angle between the mean planes of the benzofuran ring system [maximum deviation = 0.037 (2) Å] and the 4-fluorobenzene ring is 71.92 (5)°. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, molecules are linked by π–π stacking bet...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257165/ https://www.ncbi.nlm.nih.gov/pubmed/25484681 http://dx.doi.org/10.1107/S1600536814019229 |
Sumario: | In the title compound, C(17)H(14)ClFO(2)S, the dihedral angle between the mean planes of the benzofuran ring system [maximum deviation = 0.037 (2) Å] and the 4-fluorobenzene ring is 71.92 (5)°. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, molecules are linked by π–π stacking between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.7103 (10) Å]. These molecules are further linked by C—S⋯π [S⋯centroid = 3.570 (1) Å] and C—H⋯O interactions, resulting in a three-dimensional supramolecular network. |
---|