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Crystal structure of 5-chloro-3-(4-fluoro­phenyl­sulfin­yl)-2,4,6-trimethyl-1-benzo­furan

In the title compound, C(17)H(14)ClFO(2)S, the dihedral angle between the mean planes of the benzo­furan ring system [maximum deviation = 0.037 (2) Å] and the 4-fluoro­benzene ring is 71.92 (5)°. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked by π–π stacking bet...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257165/
https://www.ncbi.nlm.nih.gov/pubmed/25484681
http://dx.doi.org/10.1107/S1600536814019229
Descripción
Sumario:In the title compound, C(17)H(14)ClFO(2)S, the dihedral angle between the mean planes of the benzo­furan ring system [maximum deviation = 0.037 (2) Å] and the 4-fluoro­benzene ring is 71.92 (5)°. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked by π–π stacking between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.7103 (10) Å]. These mol­ecules are further linked by C—S⋯π [S⋯centroid = 3.570 (1) Å] and C—H⋯O inter­actions, resulting in a three-dimensional supra­molecular network.