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Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis{[(1H-pyrrol-2-yl)methylidene]ami...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257179/ https://www.ncbi.nlm.nih.gov/pubmed/25484654 http://dx.doi.org/10.1107/S1600536814020406 |
Sumario: | The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino}propan-2-olate ligands, resulting in a distorted octahedral geometry. The average Mn—ligand bond lengths in the two complex molecules are 2.074 and 2.079 Å. In the crystal, intermolecular N—H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent molecule and the nitrate ion are connected by an O—H⋯O hydrogen bond. |
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