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Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate

The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]ami...

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Autores principales: Ahn, Seoung Hyun, Shin, Jong Won, Moon, Dohyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257179/
https://www.ncbi.nlm.nih.gov/pubmed/25484654
http://dx.doi.org/10.1107/S1600536814020406
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author Ahn, Seoung Hyun
Shin, Jong Won
Moon, Dohyun
author_facet Ahn, Seoung Hyun
Shin, Jong Won
Moon, Dohyun
author_sort Ahn, Seoung Hyun
collection PubMed
description The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino}­propan-2-olate ligands, resulting in a distorted octa­hedral geometry. The average Mn—ligand bond lengths in the two complex mol­ecules are 2.074 and 2.079 Å. In the crystal, inter­molecular N—H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent mol­ecule and the nitrate ion are connected by an O—H⋯O hydrogen bond.
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spelling pubmed-42571792014-12-05 Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate Ahn, Seoung Hyun Shin, Jong Won Moon, Dohyun Acta Crystallogr Sect E Struct Rep Online Research Communications The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino}­propan-2-olate ligands, resulting in a distorted octa­hedral geometry. The average Mn—ligand bond lengths in the two complex mol­ecules are 2.074 and 2.079 Å. In the crystal, inter­molecular N—H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent mol­ecule and the nitrate ion are connected by an O—H⋯O hydrogen bond. International Union of Crystallography 2014-09-17 /pmc/articles/PMC4257179/ /pubmed/25484654 http://dx.doi.org/10.1107/S1600536814020406 Text en © Ahn et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ahn, Seoung Hyun
Shin, Jong Won
Moon, Dohyun
Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
title Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
title_full Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
title_fullStr Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
title_full_unstemmed Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
title_short Crystal structure of bis­(1,3-bis­{[(1H-pyrrol-2-yl)methyl­idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
title_sort crystal structure of bis­(1,3-bis­{[(1h-pyrrol-2-yl)methyl­idene]amino-κn}propan-2-olato-κo)manganese(iii) nitrate methanol monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257179/
https://www.ncbi.nlm.nih.gov/pubmed/25484654
http://dx.doi.org/10.1107/S1600536814020406
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