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Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate
The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis{[(1H-pyrrol-2-yl)methylidene]ami...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257179/ https://www.ncbi.nlm.nih.gov/pubmed/25484654 http://dx.doi.org/10.1107/S1600536814020406 |
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author | Ahn, Seoung Hyun Shin, Jong Won Moon, Dohyun |
author_facet | Ahn, Seoung Hyun Shin, Jong Won Moon, Dohyun |
author_sort | Ahn, Seoung Hyun |
collection | PubMed |
description | The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino}propan-2-olate ligands, resulting in a distorted octahedral geometry. The average Mn—ligand bond lengths in the two complex molecules are 2.074 and 2.079 Å. In the crystal, intermolecular N—H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent molecule and the nitrate ion are connected by an O—H⋯O hydrogen bond. |
format | Online Article Text |
id | pubmed-4257179 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42571792014-12-05 Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate Ahn, Seoung Hyun Shin, Jong Won Moon, Dohyun Acta Crystallogr Sect E Struct Rep Online Research Communications The asymmetric unit of the title compound, [Mn(C(13)H(15)N(4)O)(2)]NO(3)·CH(3)OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino}propan-2-olate ligands, resulting in a distorted octahedral geometry. The average Mn—ligand bond lengths in the two complex molecules are 2.074 and 2.079 Å. In the crystal, intermolecular N—H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent molecule and the nitrate ion are connected by an O—H⋯O hydrogen bond. International Union of Crystallography 2014-09-17 /pmc/articles/PMC4257179/ /pubmed/25484654 http://dx.doi.org/10.1107/S1600536814020406 Text en © Ahn et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Ahn, Seoung Hyun Shin, Jong Won Moon, Dohyun Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate |
title | Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate |
title_full | Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate |
title_fullStr | Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate |
title_full_unstemmed | Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate |
title_short | Crystal structure of bis(1,3-bis{[(1H-pyrrol-2-yl)methylidene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate |
title_sort | crystal structure of bis(1,3-bis{[(1h-pyrrol-2-yl)methylidene]amino-κn}propan-2-olato-κo)manganese(iii) nitrate methanol monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257179/ https://www.ncbi.nlm.nih.gov/pubmed/25484654 http://dx.doi.org/10.1107/S1600536814020406 |
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