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Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate

The title ionic salt, C(21)H(20)P(+)·C(24)H(20)B(−), crystallized with two independent vinyl­tri­phenyl­phospho­nium cations and two independent tetra­phenyl­borate anions per asymmetric unit. These four independent moieties contain nearly perfect tetra­hedral symmetry about their respective central...

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Autores principales: Bradfield, Joseph L., Braun, Richard A., White, Frankie, Hendrich, Jeffrey M., Sykora, Richard E., Mirjafari, Arsalan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257183/
https://www.ncbi.nlm.nih.gov/pubmed/25484719
http://dx.doi.org/10.1107/S1600536814021357
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author Bradfield, Joseph L.
Braun, Richard A.
White, Frankie
Hendrich, Jeffrey M.
Sykora, Richard E.
Mirjafari, Arsalan
author_facet Bradfield, Joseph L.
Braun, Richard A.
White, Frankie
Hendrich, Jeffrey M.
Sykora, Richard E.
Mirjafari, Arsalan
author_sort Bradfield, Joseph L.
collection PubMed
description The title ionic salt, C(21)H(20)P(+)·C(24)H(20)B(−), crystallized with two independent vinyl­tri­phenyl­phospho­nium cations and two independent tetra­phenyl­borate anions per asymmetric unit. These four independent moieties contain nearly perfect tetra­hedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other inter­molecular inter­actions present.
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spelling pubmed-42571832014-12-05 Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate Bradfield, Joseph L. Braun, Richard A. White, Frankie Hendrich, Jeffrey M. Sykora, Richard E. Mirjafari, Arsalan Acta Crystallogr Sect E Struct Rep Online Data Reports The title ionic salt, C(21)H(20)P(+)·C(24)H(20)B(−), crystallized with two independent vinyl­tri­phenyl­phospho­nium cations and two independent tetra­phenyl­borate anions per asymmetric unit. These four independent moieties contain nearly perfect tetra­hedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other inter­molecular inter­actions present. International Union of Crystallography 2014-09-30 /pmc/articles/PMC4257183/ /pubmed/25484719 http://dx.doi.org/10.1107/S1600536814021357 Text en © Bradfield et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Bradfield, Joseph L.
Braun, Richard A.
White, Frankie
Hendrich, Jeffrey M.
Sykora, Richard E.
Mirjafari, Arsalan
Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
title Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
title_full Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
title_fullStr Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
title_full_unstemmed Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
title_short Crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
title_sort crystal structure of tri­phenyl(vinyl)­phospho­nium tetra­phenyl­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257183/
https://www.ncbi.nlm.nih.gov/pubmed/25484719
http://dx.doi.org/10.1107/S1600536814021357
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