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Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate
The title ionic salt, C(21)H(20)P(+)·C(24)H(20)B(−), crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257183/ https://www.ncbi.nlm.nih.gov/pubmed/25484719 http://dx.doi.org/10.1107/S1600536814021357 |
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author | Bradfield, Joseph L. Braun, Richard A. White, Frankie Hendrich, Jeffrey M. Sykora, Richard E. Mirjafari, Arsalan |
author_facet | Bradfield, Joseph L. Braun, Richard A. White, Frankie Hendrich, Jeffrey M. Sykora, Richard E. Mirjafari, Arsalan |
author_sort | Bradfield, Joseph L. |
collection | PubMed |
description | The title ionic salt, C(21)H(20)P(+)·C(24)H(20)B(−), crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present. |
format | Online Article Text |
id | pubmed-4257183 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42571832014-12-05 Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate Bradfield, Joseph L. Braun, Richard A. White, Frankie Hendrich, Jeffrey M. Sykora, Richard E. Mirjafari, Arsalan Acta Crystallogr Sect E Struct Rep Online Data Reports The title ionic salt, C(21)H(20)P(+)·C(24)H(20)B(−), crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present. International Union of Crystallography 2014-09-30 /pmc/articles/PMC4257183/ /pubmed/25484719 http://dx.doi.org/10.1107/S1600536814021357 Text en © Bradfield et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Bradfield, Joseph L. Braun, Richard A. White, Frankie Hendrich, Jeffrey M. Sykora, Richard E. Mirjafari, Arsalan Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
title | Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
title_full | Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
title_fullStr | Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
title_full_unstemmed | Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
title_short | Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
title_sort | crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257183/ https://www.ncbi.nlm.nih.gov/pubmed/25484719 http://dx.doi.org/10.1107/S1600536814021357 |
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