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Crystal structure of 3-{1′-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]ferrocenyl}-4-bromo­thio­phene

The mol­ecular structure of the title compound, [Fe(C(9)H(6)BrS)(C(13)H(7)F(6))], consists of a ferrocene backbone with a bis­(tri­fluoro­meth­yl)phenyl group at one cyclo­penta­dienyl ring and a thio­phene heterocycle at the other cyclo­penta­dienyl ring. The latter is disordered over two sets of s...

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Detalles Bibliográficos
Autores principales: Poppitz, Elisabeth A., Korb, Marcus, Lang, Heinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257188/
https://www.ncbi.nlm.nih.gov/pubmed/25484662
http://dx.doi.org/10.1107/S1600536814020674
Descripción
Sumario:The mol­ecular structure of the title compound, [Fe(C(9)H(6)BrS)(C(13)H(7)F(6))], consists of a ferrocene backbone with a bis­(tri­fluoro­meth­yl)phenyl group at one cyclo­penta­dienyl ring and a thio­phene heterocycle at the other cyclo­penta­dienyl ring. The latter is disordered over two sets of sites in a 0.6:0.4 ratio. In the crystal structure, intra­molecular π–π inter­actions between the thienyl and the phenyl substituent [centroid–centroid distance 3.695 (4) Å] and additional weak T-shaped π–π inter­actions between the thienyl and the phenyl-substituted cyclo­penta­dienyl ring [4.688 (6) Å] consolidate the crystal packing.