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Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate
The title compound, C(20)H(23)N(3)O(6)·CH(3)OH, was synthesized by [3 + 2] cycloaddition of (Z)-2,3-bis(3,4,5-trimethoxyphenyl)acrylonitrile with sodium azide and ammonium chloride in DMF/water. The central nitrogen of the triazole ring is protonated. The dihedral angles between the triazole...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257191/ https://www.ncbi.nlm.nih.gov/pubmed/25484710 http://dx.doi.org/10.1107/S1600536814020911 |
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| author | Madadi, Nikhil Reddy Penthala, Narsimha Reddy Bommagani, Shobanbabu Parkin, Sean Crooks, Peter A. |
| author_facet | Madadi, Nikhil Reddy Penthala, Narsimha Reddy Bommagani, Shobanbabu Parkin, Sean Crooks, Peter A. |
| author_sort | Madadi, Nikhil Reddy |
| collection | PubMed |
| description | The title compound, C(20)H(23)N(3)O(6)·CH(3)OH, was synthesized by [3 + 2] cycloaddition of (Z)-2,3-bis(3,4,5-trimethoxyphenyl)acrylonitrile with sodium azide and ammonium chloride in DMF/water. The central nitrogen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-trimethoxyphenyl ring planes are 34.31 (4) and 45.03 (5)°, while that between the 3,4,5-trimethoxyphenyl rings is 51.87 (5)°. In the crystal, the molecules, along with two methanol solvent molecules are linked into an R (4) (4)(10) centrosymmetric dimer by N—H⋯O and O—H⋯N hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-4257191 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42571912014-12-05 Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate Madadi, Nikhil Reddy Penthala, Narsimha Reddy Bommagani, Shobanbabu Parkin, Sean Crooks, Peter A. Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(20)H(23)N(3)O(6)·CH(3)OH, was synthesized by [3 + 2] cycloaddition of (Z)-2,3-bis(3,4,5-trimethoxyphenyl)acrylonitrile with sodium azide and ammonium chloride in DMF/water. The central nitrogen of the triazole ring is protonated. The dihedral angles between the triazole ring and the 3,4,5-trimethoxyphenyl ring planes are 34.31 (4) and 45.03 (5)°, while that between the 3,4,5-trimethoxyphenyl rings is 51.87 (5)°. In the crystal, the molecules, along with two methanol solvent molecules are linked into an R (4) (4)(10) centrosymmetric dimer by N—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2014-09-24 /pmc/articles/PMC4257191/ /pubmed/25484710 http://dx.doi.org/10.1107/S1600536814020911 Text en © Madadi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Madadi, Nikhil Reddy Penthala, Narsimha Reddy Bommagani, Shobanbabu Parkin, Sean Crooks, Peter A. Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate |
| title | Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate |
| title_full | Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate |
| title_fullStr | Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate |
| title_full_unstemmed | Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate |
| title_short | Crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2H-1,2,3-triazole methanol monosolvate |
| title_sort | crystal structure of 4,5-bis(3,4,5-trimethoxyphenyl)-2h-1,2,3-triazole methanol monosolvate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257191/ https://www.ncbi.nlm.nih.gov/pubmed/25484710 http://dx.doi.org/10.1107/S1600536814020911 |
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