Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal

The title penta­cyclo­undecane cage derivative, C(13)H(14)OS(2), was identified during a thio­ketalization reaction. The reaction selectively gave the title compound and the product corresponding to bis-ketal was not formed. The title compound exhibits unusual Csp (3)—Csp (3) single bond lengths ran...

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Autores principales: Kotha, Sambasivarao, Sreenivasachary, Nampalli, Deodhar, Deepak, Shaikh, Mobin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257192/
https://www.ncbi.nlm.nih.gov/pubmed/25484664
http://dx.doi.org/10.1107/S1600536814020790
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author Kotha, Sambasivarao
Sreenivasachary, Nampalli
Deodhar, Deepak
Shaikh, Mobin
author_facet Kotha, Sambasivarao
Sreenivasachary, Nampalli
Deodhar, Deepak
Shaikh, Mobin
author_sort Kotha, Sambasivarao
collection PubMed
description The title penta­cyclo­undecane cage derivative, C(13)H(14)OS(2), was identified during a thio­ketalization reaction. The reaction selectively gave the title compound and the product corresponding to bis-ketal was not formed. The title compound exhibits unusual Csp (3)—Csp (3) single bond lengths ranging from 1.495 (3) to 1.581 (2) and strained bond angles as small as 89.29 (12) and as large as 115.11 (11)°.
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spelling pubmed-42571922014-12-05 Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal Kotha, Sambasivarao Sreenivasachary, Nampalli Deodhar, Deepak Shaikh, Mobin Acta Crystallogr Sect E Struct Rep Online Research Communications The title penta­cyclo­undecane cage derivative, C(13)H(14)OS(2), was identified during a thio­ketalization reaction. The reaction selectively gave the title compound and the product corresponding to bis-ketal was not formed. The title compound exhibits unusual Csp (3)—Csp (3) single bond lengths ranging from 1.495 (3) to 1.581 (2) and strained bond angles as small as 89.29 (12) and as large as 115.11 (11)°. International Union of Crystallography 2014-09-24 /pmc/articles/PMC4257192/ /pubmed/25484664 http://dx.doi.org/10.1107/S1600536814020790 Text en © Kotha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kotha, Sambasivarao
Sreenivasachary, Nampalli
Deodhar, Deepak
Shaikh, Mobin
Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
title Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
title_full Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
title_fullStr Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
title_full_unstemmed Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
title_short Crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
title_sort crystal structure of the cage derivative penta­cyclo­[5.4.0.0(2,6).0(3,10).0(5,9)]undeca-8,11-dione ethyl­ene di­thio­ketal
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257192/
https://www.ncbi.nlm.nih.gov/pubmed/25484664
http://dx.doi.org/10.1107/S1600536814020790
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