Cargando…
Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6) O (1),O (3):O (3):O (1′),O (3′):O (1′))tetrakis(triphenylphosphane-κP)tetrasilver(I)
In the tetranuclear molecule of the title compound, [Ag(4)(C(9)H(10)O(4))(2)(C(18)H(15)P)(4)], the Ag(I) ion is coordinated by one P and three O atoms in a considerably distorted tetrahedral environment. The two 2,2-diallylmalonate anions bridge four Ag(I) ions in a μ(4)-(κ(6) O (1),O (3):O (3)...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257203/ https://www.ncbi.nlm.nih.gov/pubmed/25484645 http://dx.doi.org/10.1107/S1600536814019394 |
| _version_ | 1782347699855556608 |
|---|---|
| author | Frenzel, Peter Jakob, Alexander Schaarschmidt, Dieter Rüffer, Tobias Lang, Heinrich |
| author_facet | Frenzel, Peter Jakob, Alexander Schaarschmidt, Dieter Rüffer, Tobias Lang, Heinrich |
| author_sort | Frenzel, Peter |
| collection | PubMed |
| description | In the tetranuclear molecule of the title compound, [Ag(4)(C(9)H(10)O(4))(2)(C(18)H(15)P)(4)], the Ag(I) ion is coordinated by one P and three O atoms in a considerably distorted tetrahedral environment. The two 2,2-diallylmalonate anions bridge four Ag(I) ions in a μ(4)-(κ(6) O (1),O (3):O (3):O (1′),O (3′):O (1′)) mode, setting up an Ag(4)O(8)P(4) core (point group symmetry -4..) of corner-sharing tetrahedra. The shortest intramolecular Ag⋯Ag distance of 3.9510 (3) Å reveals that no direct d (10)⋯d (10) interactions are present. Four weak intramolecular C—H⋯O hydrogen bonds are observed in the crystal structure of the title compound, which most likely stabilize the tetranuclear silver core. |
| format | Online Article Text |
| id | pubmed-4257203 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42572032014-12-05 Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6) O (1),O (3):O (3):O (1′),O (3′):O (1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) Frenzel, Peter Jakob, Alexander Schaarschmidt, Dieter Rüffer, Tobias Lang, Heinrich Acta Crystallogr Sect E Struct Rep Online Research Communications In the tetranuclear molecule of the title compound, [Ag(4)(C(9)H(10)O(4))(2)(C(18)H(15)P)(4)], the Ag(I) ion is coordinated by one P and three O atoms in a considerably distorted tetrahedral environment. The two 2,2-diallylmalonate anions bridge four Ag(I) ions in a μ(4)-(κ(6) O (1),O (3):O (3):O (1′),O (3′):O (1′)) mode, setting up an Ag(4)O(8)P(4) core (point group symmetry -4..) of corner-sharing tetrahedra. The shortest intramolecular Ag⋯Ag distance of 3.9510 (3) Å reveals that no direct d (10)⋯d (10) interactions are present. Four weak intramolecular C—H⋯O hydrogen bonds are observed in the crystal structure of the title compound, which most likely stabilize the tetranuclear silver core. International Union of Crystallography 2014-09-10 /pmc/articles/PMC4257203/ /pubmed/25484645 http://dx.doi.org/10.1107/S1600536814019394 Text en © Frenzel et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Frenzel, Peter Jakob, Alexander Schaarschmidt, Dieter Rüffer, Tobias Lang, Heinrich Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6) O (1),O (3):O (3):O (1′),O (3′):O (1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) |
| title | Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6)
O
(1),O
(3):O
(3):O
(1′),O
(3′):O
(1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) |
| title_full | Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6)
O
(1),O
(3):O
(3):O
(1′),O
(3′):O
(1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) |
| title_fullStr | Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6)
O
(1),O
(3):O
(3):O
(1′),O
(3′):O
(1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) |
| title_full_unstemmed | Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6)
O
(1),O
(3):O
(3):O
(1′),O
(3′):O
(1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) |
| title_short | Crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6)
O
(1),O
(3):O
(3):O
(1′),O
(3′):O
(1′))tetrakis(triphenylphosphane-κP)tetrasilver(I) |
| title_sort | crystal structure of cyclo-bis(μ(4)-2,2-diallylmalonato-κ(6)
o
(1),o
(3):o
(3):o
(1′),o
(3′):o
(1′))tetrakis(triphenylphosphane-κp)tetrasilver(i) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257203/ https://www.ncbi.nlm.nih.gov/pubmed/25484645 http://dx.doi.org/10.1107/S1600536814019394 |
| work_keys_str_mv | AT frenzelpeter crystalstructureofcyclobism422diallylmalonatok6o1o3o3o1o3o1tetrakistriphenylphosphanekptetrasilveri AT jakobalexander crystalstructureofcyclobism422diallylmalonatok6o1o3o3o1o3o1tetrakistriphenylphosphanekptetrasilveri AT schaarschmidtdieter crystalstructureofcyclobism422diallylmalonatok6o1o3o3o1o3o1tetrakistriphenylphosphanekptetrasilveri AT ruffertobias crystalstructureofcyclobism422diallylmalonatok6o1o3o3o1o3o1tetrakistriphenylphosphanekptetrasilveri AT langheinrich crystalstructureofcyclobism422diallylmalonatok6o1o3o3o1o3o1tetrakistriphenylphosphanekptetrasilveri |