Cargando…
Crystal structure of bis{μ-4,4′-[1,3-phenylenebis(oxy)]dibenzoato-κ(4) O,O′:O′′,O′′′}bis[(1,10-phenanthroline-κ(2) N,N′)zinc(II)] dihydrate
Two 4,4′-[1,3-phenylenebis(oxy)]dibenzoate anions bridge two 1,10-phenanthroline-chelated Zn(II) cations about a center of inversion to generate the dinuclear title compound, [Zn(2)(C(20)H(12)O(6))(2)(C(12)H(8)N(2))(2)]·2H(2)O. The geometry about the Zn(II) atom is a distorted octahedron. In the...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257206/ https://www.ncbi.nlm.nih.gov/pubmed/25484671 http://dx.doi.org/10.1107/S1600536814018340 |
Sumario: | Two 4,4′-[1,3-phenylenebis(oxy)]dibenzoate anions bridge two 1,10-phenanthroline-chelated Zn(II) cations about a center of inversion to generate the dinuclear title compound, [Zn(2)(C(20)H(12)O(6))(2)(C(12)H(8)N(2))(2)]·2H(2)O. The geometry about the Zn(II) atom is a distorted octahedron. In the crystal, the molecules are connected by classical O—H⋯O hydrogen bonds, weak C—H⋯O hydrogen bonds and C—H⋯π interactions, forming a three dimensional network. π–π stacking is also observed between aromatic rings of adjacent molecules, centroid–centroid distances are 3.753 (2), 3.5429 (16) and 3.5695 (17) Å. |
---|