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Crystal structure of bis­{μ-4,4′-[1,3-phenyl­enebis(­oxy)]dibenzoato-κ(4) O,O′:O′′,O′′′}bis[(1,10-phenanthroline-κ(2) N,N′)zinc(II)] dihydrate

Two 4,4′-[1,3-phenyl­enebis(­oxy)]dibenzoate anions bridge two 1,10-phenanthroline-chelated Zn(II) cations about a center of inversion to generate the dinuclear title compound, [Zn(2)(C(20)H(12)O(6))(2)(C(12)H(8)N(2))(2)]·2H(2)O. The geometry about the Zn(II) atom is a distorted octa­hedron. In the...

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Detalles Bibliográficos
Autores principales: Li, Ya-Ping, Han, Li-Ying, Ming, Julia, Zang, Hu, Su, Guan-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257206/
https://www.ncbi.nlm.nih.gov/pubmed/25484671
http://dx.doi.org/10.1107/S1600536814018340
Descripción
Sumario:Two 4,4′-[1,3-phenyl­enebis(­oxy)]dibenzoate anions bridge two 1,10-phenanthroline-chelated Zn(II) cations about a center of inversion to generate the dinuclear title compound, [Zn(2)(C(20)H(12)O(6))(2)(C(12)H(8)N(2))(2)]·2H(2)O. The geometry about the Zn(II) atom is a distorted octa­hedron. In the crystal, the mol­ecules are connected by classical O—H⋯O hydrogen bonds, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming a three dimensional network. π–π stacking is also observed between aromatic rings of adjacent mol­ecules, centroid–centroid distances are 3.753 (2), 3.5429 (16) and 3.5695 (17) Å.