Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate

In the title salt, (C(2)H(10)N(2))(3)[Pr(2)(SO(4))(6)]·6H(2)O, the Pr(III) cation is surrounded ninefold by five sulfate groups (two monodentate and three chelating) and by one water mol­ecule [range of Pr—O bond lengths 2.383 (3) to 2.582 (3) Å]. The [Pr(SO(4))(5)(H(2)O)] groups are arranged in she...

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Detalles Bibliográficos
Autor principal: Held, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257211/
https://www.ncbi.nlm.nih.gov/pubmed/25484661
http://dx.doi.org/10.1107/S1600536814020704
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author Held, Peter
author_facet Held, Peter
author_sort Held, Peter
collection PubMed
description In the title salt, (C(2)H(10)N(2))(3)[Pr(2)(SO(4))(6)]·6H(2)O, the Pr(III) cation is surrounded ninefold by five sulfate groups (two monodentate and three chelating) and by one water mol­ecule [range of Pr—O bond lengths 2.383 (3) to 2.582 (3) Å]. The [Pr(SO(4))(5)(H(2)O)] groups are arranged in sheets parallel to (010). Two crystal water mol­ecules and two ethyl­enedi­ammonium cations (one with point group symmetry -1) connect the sheets via O—H⋯O and N—H⋯O hydrogen bonds from weak up to medium strength into a three-dimensional framework structure.
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spelling pubmed-42572112014-12-05 Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate Held, Peter Acta Crystallogr Sect E Struct Rep Online Research Communications In the title salt, (C(2)H(10)N(2))(3)[Pr(2)(SO(4))(6)]·6H(2)O, the Pr(III) cation is surrounded ninefold by five sulfate groups (two monodentate and three chelating) and by one water mol­ecule [range of Pr—O bond lengths 2.383 (3) to 2.582 (3) Å]. The [Pr(SO(4))(5)(H(2)O)] groups are arranged in sheets parallel to (010). Two crystal water mol­ecules and two ethyl­enedi­ammonium cations (one with point group symmetry -1) connect the sheets via O—H⋯O and N—H⋯O hydrogen bonds from weak up to medium strength into a three-dimensional framework structure. International Union of Crystallography 2014-09-20 /pmc/articles/PMC4257211/ /pubmed/25484661 http://dx.doi.org/10.1107/S1600536814020704 Text en © Peter Held 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Held, Peter
Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate
title Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate
title_full Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate
title_fullStr Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate
title_full_unstemmed Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate
title_short Crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(III) hexa­hydrate
title_sort crystal structure of tris­(ethyl­enedi­ammonium) hexasulfatopraseodymium(iii) hexa­hydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257211/
https://www.ncbi.nlm.nih.gov/pubmed/25484661
http://dx.doi.org/10.1107/S1600536814020704
work_keys_str_mv AT heldpeter crystalstructureoftrisethylenediammoniumhexasulfatopraseodymiumiiihexahydrate

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