Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin

In the title compound, C(44)H(37)BN(4)O(2), the dihedral angle between the plane of the porphyrin macrocycle ring system [r.m.s. deviation = 0.159 (1) Å] and those of three phenyl rings are 66.11 (4), 74.75 (4) and 57.00 (4)°. The conformational distortion is characterized by a mixture of ruffled, s...

Descripción completa

Detalles Bibliográficos
Autores principales: Senge, Mathias O., Eckhardt, Hans-Georg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257212/
https://www.ncbi.nlm.nih.gov/pubmed/25484685
http://dx.doi.org/10.1107/S1600536814019680
_version_ 1782347701971582976
author Senge, Mathias O.
Eckhardt, Hans-Georg
author_facet Senge, Mathias O.
Eckhardt, Hans-Georg
author_sort Senge, Mathias O.
collection PubMed
description In the title compound, C(44)H(37)BN(4)O(2), the dihedral angle between the plane of the porphyrin macrocycle ring system [r.m.s. deviation = 0.159 (1) Å] and those of three phenyl rings are 66.11 (4), 74.75 (4) and 57.00 (4)°. The conformational distortion is characterized by a mixture of ruffled, saddle and in-plane distortion modes. In the crystal, the porphyrin mol­ecules are linked by C—H⋯π inter­actions into supra­molecular chains running along the a-axis direction. A pair of bifurcated N—H⋯(N,N) hydrogen bonds occur across the central region of the macrocycle.
format Online
Article
Text
id pubmed-4257212
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42572122014-12-05 Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin Senge, Mathias O. Eckhardt, Hans-Georg Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(44)H(37)BN(4)O(2), the dihedral angle between the plane of the porphyrin macrocycle ring system [r.m.s. deviation = 0.159 (1) Å] and those of three phenyl rings are 66.11 (4), 74.75 (4) and 57.00 (4)°. The conformational distortion is characterized by a mixture of ruffled, saddle and in-plane distortion modes. In the crystal, the porphyrin mol­ecules are linked by C—H⋯π inter­actions into supra­molecular chains running along the a-axis direction. A pair of bifurcated N—H⋯(N,N) hydrogen bonds occur across the central region of the macrocycle. International Union of Crystallography 2014-09-06 /pmc/articles/PMC4257212/ /pubmed/25484685 http://dx.doi.org/10.1107/S1600536814019680 Text en © Senge and Eckhardt 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Senge, Mathias O.
Eckhardt, Hans-Georg
Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
title Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
title_full Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
title_fullStr Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
title_full_unstemmed Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
title_short Crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
title_sort crystal structure of 5,10,15-triphenyl-20-(4,4,5,5-tetra­methyl-1,3,2-dioxaborolan-2-yl)porphyrin
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257212/
https://www.ncbi.nlm.nih.gov/pubmed/25484685
http://dx.doi.org/10.1107/S1600536814019680
work_keys_str_mv AT sengemathiaso crystalstructureof51015triphenyl204455tetramethyl132dioxaborolan2ylporphyrin
AT eckhardthansgeorg crystalstructureof51015triphenyl204455tetramethyl132dioxaborolan2ylporphyrin

Ejemplares similares