Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)

The title compound, [Mn(C(48)H(36)N(4))(N)], is a manganese(V) complex with the transition metal in a square-pyramidal coordination geometry and a nitride as the axial ligand. The complex resides on a crystallographic inversion center and only one half of it is symmetry independent. The Mn(V) atom a...

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Autores principales: Shields, Mason R., Guzei, Ilia A., Goll, James G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257217/
https://www.ncbi.nlm.nih.gov/pubmed/25484663
http://dx.doi.org/10.1107/S1600536814020558
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author Shields, Mason R.
Guzei, Ilia A.
Goll, James G.
author_facet Shields, Mason R.
Guzei, Ilia A.
Goll, James G.
author_sort Shields, Mason R.
collection PubMed
description The title compound, [Mn(C(48)H(36)N(4))(N)], is a manganese(V) complex with the transition metal in a square-pyramidal coordination geometry and a nitride as the axial ligand. The complex resides on a crystallographic inversion center and only one half of it is symmetry independent. The Mn(V) atom and the nitride N atom are equally disordered across the inversion center. The Mn N distance is 1.516 (4) Å. The Mn(V) atom is displaced from the plane defined by the four equatorial nitro­gen atoms toward the nitride ligand by 0.3162 (6) Å.
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spelling pubmed-42572172014-12-05 Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V) Shields, Mason R. Guzei, Ilia A. Goll, James G. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, [Mn(C(48)H(36)N(4))(N)], is a manganese(V) complex with the transition metal in a square-pyramidal coordination geometry and a nitride as the axial ligand. The complex resides on a crystallographic inversion center and only one half of it is symmetry independent. The Mn(V) atom and the nitride N atom are equally disordered across the inversion center. The Mn N distance is 1.516 (4) Å. The Mn(V) atom is displaced from the plane defined by the four equatorial nitro­gen atoms toward the nitride ligand by 0.3162 (6) Å. International Union of Crystallography 2014-09-24 /pmc/articles/PMC4257217/ /pubmed/25484663 http://dx.doi.org/10.1107/S1600536814020558 Text en © Shields et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shields, Mason R.
Guzei, Ilia A.
Goll, James G.
Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)
title Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)
title_full Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)
title_fullStr Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)
title_full_unstemmed Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)
title_short Crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(V)
title_sort crystal structure of nitrido[5,10,15,20-tetra­kis(4-methylphenyl)­porphyrinato]­manganese(v)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257217/
https://www.ncbi.nlm.nih.gov/pubmed/25484663
http://dx.doi.org/10.1107/S1600536814020558
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