Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)

The title compound, [Al(CH(3))(2)(C(30)H(41)O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH(3))(3) in a nitro­gen atmosphere. In the mol­ecule, the coordination geometry around the Al(III) atom is slightly distorted C(2)O trigonal (the sum of the bond angles sub...

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Detalles Bibliográficos
Autores principales: Wang, Lei, Yang, Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257224/
https://www.ncbi.nlm.nih.gov/pubmed/25484677
http://dx.doi.org/10.1107/S1600536814020492
Descripción
Sumario:The title compound, [Al(CH(3))(2)(C(30)H(41)O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH(3))(3) in a nitro­gen atmosphere. In the mol­ecule, the coordination geometry around the Al(III) atom is slightly distorted C(2)O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds. The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°]. There is no inter­molecular hydrogen bonding in the crystal structure.

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