Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)

The title compound, [Al(CH(3))(2)(C(30)H(41)O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH(3))(3) in a nitro­gen atmosphere. In the mol­ecule, the coordination geometry around the Al(III) atom is slightly distorted C(2)O trigonal (the sum of the bond angles sub...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Lei, Yang, Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257224/
https://www.ncbi.nlm.nih.gov/pubmed/25484677
http://dx.doi.org/10.1107/S1600536814020492
_version_ 1782347704757649408
author Wang, Lei
Yang, Li
author_facet Wang, Lei
Yang, Li
author_sort Wang, Lei
collection PubMed
description The title compound, [Al(CH(3))(2)(C(30)H(41)O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH(3))(3) in a nitro­gen atmosphere. In the mol­ecule, the coordination geometry around the Al(III) atom is slightly distorted C(2)O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds. The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°]. There is no inter­molecular hydrogen bonding in the crystal structure.
format Online
Article
Text
id pubmed-4257224
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42572242014-12-05 Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III) Wang, Lei Yang, Li Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, [Al(CH(3))(2)(C(30)H(41)O)] is synthesized by the reaction of 2,6-di-adamantyl-4-tert-butyl-phenol with Al(CH(3))(3) in a nitro­gen atmosphere. In the mol­ecule, the coordination geometry around the Al(III) atom is slightly distorted C(2)O trigonal (the sum of the bond angles subtended at Al atom being 359.9°), which is rarely reported for organometallic aluminium compounds. The coordination plane is approximately perpendicular to the benzene ring [the dihedral angle = 87.73 (16)°]. There is no inter­molecular hydrogen bonding in the crystal structure. International Union of Crystallography 2014-09-24 /pmc/articles/PMC4257224/ /pubmed/25484677 http://dx.doi.org/10.1107/S1600536814020492 Text en © Wang and Yang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Wang, Lei
Yang, Li
Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)
title Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)
title_full Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)
title_fullStr Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)
title_full_unstemmed Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)
title_short Crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κO]dimethylaluminium(III)
title_sort crystal structure of [2,6-bis(adamantan-1-yl)-4-tert-butylphenolato-κo]dimethylaluminium(iii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257224/
https://www.ncbi.nlm.nih.gov/pubmed/25484677
http://dx.doi.org/10.1107/S1600536814020492
work_keys_str_mv AT wanglei crystalstructureof26bisadamantan1yl4tertbutylphenolatokodimethylaluminiumiii
AT yangli crystalstructureof26bisadamantan1yl4tertbutylphenolatokodimethylaluminiumiii

Ejemplares similares