Crystal structure of bis­[4-(4-chloro­benz­yl)pyridine-κN]bis­(thio­cyanato-κN)zinc

In the crystal structure of the title compound, [Zn(NCS)(2)(C(12)H(10)ClN)(2)], the Zn(2+) cation is N-coordinated by two terminally bonded thio­cyante anions and by two 4-(4-chloro­benz­yl)pyridine ligands within a slightly distorted tetra­hedron. The asymmetric unit consists of half of the discret...

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Detalles Bibliográficos
Autores principales: Werner, Julia, Neumann, Tristan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257228/
https://www.ncbi.nlm.nih.gov/pubmed/25484679
http://dx.doi.org/10.1107/S160053681402039X
Descripción
Sumario:In the crystal structure of the title compound, [Zn(NCS)(2)(C(12)H(10)ClN)(2)], the Zn(2+) cation is N-coordinated by two terminally bonded thio­cyante anions and by two 4-(4-chloro­benz­yl)pyridine ligands within a slightly distorted tetra­hedron. The asymmetric unit consists of half of the discrete complex, the central Zn(2+) cation of which is located on a twofold rotation axis. The discrete complexes are linked into layers via a weak inter­molecular hydrogen-bonding inter­action, with a H⋯Cl distance of 2.85 Å and a C—H⋯Cl angle of 151°. These layers extend parallel to the ab plane and are held together by dispersion forces only.

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