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Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3) N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate
The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with dimethylformamide (DMF) solvent molecules. The Co(II) atom has a distorted O(2)N(4) octahedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257231/ https://www.ncbi.nlm.nih.gov/pubmed/25484642 http://dx.doi.org/10.1107/S1600536814019485 |
Sumario: | The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with dimethylformamide (DMF) solvent molecules. The Co(II) atom has a distorted O(2)N(4) octahedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being cis. The coordination sphere around the Co(II) atom is geometrically different from that reported for the co-crystal [Co(C(13)H(9)N(2)O(2))(2)]·AA·H(2)O (AA is anthranilic acid). One of the DMF solvent molecules was modelled as being disordered about a crystallographic inversion centre with half-occupancy. The crystal structure is made up from alternating layers of complex molecules and DMF molecules parallel to (010). C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing. |
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