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Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate

The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with di­methyl­formamide (DMF) solvent mol­ecules. The Co(II) atom has a distorted O(2)N(4) octa­hedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being...

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Autores principales: Buvaylo, Elena A., Kokozay, Vladimir N., Vassilyeva, Olga Yu., Skelton, Brian W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257231/
https://www.ncbi.nlm.nih.gov/pubmed/25484642
http://dx.doi.org/10.1107/S1600536814019485
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author Buvaylo, Elena A.
Kokozay, Vladimir N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
author_facet Buvaylo, Elena A.
Kokozay, Vladimir N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
author_sort Buvaylo, Elena A.
collection PubMed
description The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with di­methyl­formamide (DMF) solvent mol­ecules. The Co(II) atom has a distorted O(2)N(4) octa­hedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being cis. The coordination sphere around the Co(II) atom is geometrically different from that reported for the co-crystal [Co(C(13)H(9)N(2)O(2))(2)]·AA·H(2)O (AA is anthranilic acid). One of the DMF solvent mol­ecules was modelled as being disordered about a crystallographic inversion centre with half-occupancy. The crystal structure is made up from alternating layers of complex mol­ecules and DMF mol­ecules parallel to (010). C—H⋯O hydrogen-bonding inter­actions between the complex mol­ecules and the solvent mol­ecules consolidate the crystal packing.
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spelling pubmed-42572312014-12-05 Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with di­methyl­formamide (DMF) solvent mol­ecules. The Co(II) atom has a distorted O(2)N(4) octa­hedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being cis. The coordination sphere around the Co(II) atom is geometrically different from that reported for the co-crystal [Co(C(13)H(9)N(2)O(2))(2)]·AA·H(2)O (AA is anthranilic acid). One of the DMF solvent mol­ecules was modelled as being disordered about a crystallographic inversion centre with half-occupancy. The crystal structure is made up from alternating layers of complex mol­ecules and DMF mol­ecules parallel to (010). C—H⋯O hydrogen-bonding inter­actions between the complex mol­ecules and the solvent mol­ecules consolidate the crystal packing. International Union of Crystallography 2014-09-06 /pmc/articles/PMC4257231/ /pubmed/25484642 http://dx.doi.org/10.1107/S1600536814019485 Text en © Buvaylo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Buvaylo, Elena A.
Kokozay, Vladimir N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate
title Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate
title_full Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate
title_fullStr Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate
title_full_unstemmed Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate
title_short Crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) N,N′,O)cobalt(II) N,N-di­methyl­formamide sesquisolvate
title_sort crystal structure of bis­(2-{[(pyridin-2-yl)methyl­idene]amino}­benzoato-κ(3) n,n′,o)cobalt(ii) n,n-di­methyl­formamide sesquisolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257231/
https://www.ncbi.nlm.nih.gov/pubmed/25484642
http://dx.doi.org/10.1107/S1600536814019485
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