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Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3) N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate
The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with dimethylformamide (DMF) solvent molecules. The Co(II) atom has a distorted O(2)N(4) octahedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257231/ https://www.ncbi.nlm.nih.gov/pubmed/25484642 http://dx.doi.org/10.1107/S1600536814019485 |
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author | Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. |
author_facet | Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. |
author_sort | Buvaylo, Elena A. |
collection | PubMed |
description | The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with dimethylformamide (DMF) solvent molecules. The Co(II) atom has a distorted O(2)N(4) octahedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being cis. The coordination sphere around the Co(II) atom is geometrically different from that reported for the co-crystal [Co(C(13)H(9)N(2)O(2))(2)]·AA·H(2)O (AA is anthranilic acid). One of the DMF solvent molecules was modelled as being disordered about a crystallographic inversion centre with half-occupancy. The crystal structure is made up from alternating layers of complex molecules and DMF molecules parallel to (010). C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing. |
format | Online Article Text |
id | pubmed-4257231 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572312014-12-05 Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3) N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, [Co(C(13)H(9)N(2)O(2))(2)]·1.5C(3)H(7)NO, is formed as a neutral Co(II) complex with dimethylformamide (DMF) solvent molecules. The Co(II) atom has a distorted O(2)N(4) octahedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms being cis. The coordination sphere around the Co(II) atom is geometrically different from that reported for the co-crystal [Co(C(13)H(9)N(2)O(2))(2)]·AA·H(2)O (AA is anthranilic acid). One of the DMF solvent molecules was modelled as being disordered about a crystallographic inversion centre with half-occupancy. The crystal structure is made up from alternating layers of complex molecules and DMF molecules parallel to (010). C—H⋯O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing. International Union of Crystallography 2014-09-06 /pmc/articles/PMC4257231/ /pubmed/25484642 http://dx.doi.org/10.1107/S1600536814019485 Text en © Buvaylo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Buvaylo, Elena A. Kokozay, Vladimir N. Vassilyeva, Olga Yu. Skelton, Brian W. Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3) N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate |
title | Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3)
N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate |
title_full | Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3)
N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate |
title_fullStr | Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3)
N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate |
title_full_unstemmed | Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3)
N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate |
title_short | Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3)
N,N′,O)cobalt(II) N,N-dimethylformamide sesquisolvate |
title_sort | crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ(3)
n,n′,o)cobalt(ii) n,n-dimethylformamide sesquisolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257231/ https://www.ncbi.nlm.nih.gov/pubmed/25484642 http://dx.doi.org/10.1107/S1600536814019485 |
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