Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)

In the title compound, [SbBr(C(10)H(7))(2)], the Sb(III) atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra­molecular C—H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C—H⋯B...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Hussien Abdelnasir, Hafiz Malik, Rosli, Mohd Mustaqim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257233/
https://www.ncbi.nlm.nih.gov/pubmed/25484676
http://dx.doi.org/10.1107/S1600536814020066
Descripción
Sumario:In the title compound, [SbBr(C(10)H(7))(2)], the Sb(III) atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra­molecular C—H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C—H⋯Br inter­actions link the mol­ecules into helical chains along the b-axis direction.

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