Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)

In the title compound, [SbBr(C(10)H(7))(2)], the Sb(III) atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra­molecular C—H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C—H⋯B...

Descripción completa

Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Hussien Abdelnasir, Hafiz Malik, Rosli, Mohd Mustaqim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257233/
https://www.ncbi.nlm.nih.gov/pubmed/25484676
http://dx.doi.org/10.1107/S1600536814020066
_version_ 1782347706891501568
author Shawkataly, Omar bin
Hussien Abdelnasir, Hafiz Malik
Rosli, Mohd Mustaqim
author_facet Shawkataly, Omar bin
Hussien Abdelnasir, Hafiz Malik
Rosli, Mohd Mustaqim
author_sort Shawkataly, Omar bin
collection PubMed
description In the title compound, [SbBr(C(10)H(7))(2)], the Sb(III) atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra­molecular C—H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C—H⋯Br inter­actions link the mol­ecules into helical chains along the b-axis direction.
format Online
Article
Text
id pubmed-4257233
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42572332014-12-05 Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III) Shawkataly, Omar bin Hussien Abdelnasir, Hafiz Malik Rosli, Mohd Mustaqim Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [SbBr(C(10)H(7))(2)], the Sb(III) atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra­molecular C—H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C—H⋯Br inter­actions link the mol­ecules into helical chains along the b-axis direction. International Union of Crystallography 2014-09-24 /pmc/articles/PMC4257233/ /pubmed/25484676 http://dx.doi.org/10.1107/S1600536814020066 Text en © Shawkataly et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shawkataly, Omar bin
Hussien Abdelnasir, Hafiz Malik
Rosli, Mohd Mustaqim
Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)
title Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)
title_full Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)
title_fullStr Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)
title_full_unstemmed Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)
title_short Crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(III)
title_sort crystal structure of bromido­bis­(naph­thal­en-1-yl)anti­mony(iii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257233/
https://www.ncbi.nlm.nih.gov/pubmed/25484676
http://dx.doi.org/10.1107/S1600536814020066
work_keys_str_mv AT shawkatalyomarbin crystalstructureofbromidobisnaphthalen1ylantimonyiii
AT hussienabdelnasirhafizmalik crystalstructureofbromidobisnaphthalen1ylantimonyiii
AT roslimohdmustaqim crystalstructureofbromidobisnaphthalen1ylantimonyiii

Ejemplares similares