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Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate

The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis­(2,6-diiso­propyl­phen­yl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in di­chloro­methane. The complete cation is generated by a crystallographic mir...

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Detalles Bibliográficos
Autores principales: Berger, Matthias, Auner, Norbert, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257239/
https://www.ncbi.nlm.nih.gov/pubmed/25484824
http://dx.doi.org/10.1107/S1600536814023150
Descripción
Sumario:The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis­(2,6-diiso­propyl­phen­yl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in di­chloro­methane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8 (6)°; the dihedral angle between the benzene rings is 40.7 (2)°. The anion also lies on the mirror plane and both di­chloro­methane mol­ecules are disordered across the mirror plane over two equally occupied orientations. In the crystal, the cations are linked to the anions via C—H⋯Br hydrogen bonds.