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Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate
The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in dichloromethane. The complete cation is generated by a crystallographic mir...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257239/ https://www.ncbi.nlm.nih.gov/pubmed/25484824 http://dx.doi.org/10.1107/S1600536814023150 |
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author | Berger, Matthias Auner, Norbert Bolte, Michael |
author_facet | Berger, Matthias Auner, Norbert Bolte, Michael |
author_sort | Berger, Matthias |
collection | PubMed |
description | The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in dichloromethane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8 (6)°; the dihedral angle between the benzene rings is 40.7 (2)°. The anion also lies on the mirror plane and both dichloromethane molecules are disordered across the mirror plane over two equally occupied orientations. In the crystal, the cations are linked to the anions via C—H⋯Br hydrogen bonds. |
format | Online Article Text |
id | pubmed-4257239 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572392014-12-05 Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate Berger, Matthias Auner, Norbert Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Data Reports The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in dichloromethane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8 (6)°; the dihedral angle between the benzene rings is 40.7 (2)°. The anion also lies on the mirror plane and both dichloromethane molecules are disordered across the mirror plane over two equally occupied orientations. In the crystal, the cations are linked to the anions via C—H⋯Br hydrogen bonds. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257239/ /pubmed/25484824 http://dx.doi.org/10.1107/S1600536814023150 Text en © Berger et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Berger, Matthias Auner, Norbert Bolte, Michael Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate |
title | Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate |
title_full | Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate |
title_fullStr | Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate |
title_full_unstemmed | Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate |
title_short | Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate |
title_sort | crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1h-imidazol-3-ium bromide dichloromethane disolvate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257239/ https://www.ncbi.nlm.nih.gov/pubmed/25484824 http://dx.doi.org/10.1107/S1600536814023150 |
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