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Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate

The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis­(2,6-diiso­propyl­phen­yl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in di­chloro­methane. The complete cation is generated by a crystallographic mir...

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Detalles Bibliográficos
Autores principales: Berger, Matthias, Auner, Norbert, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257239/
https://www.ncbi.nlm.nih.gov/pubmed/25484824
http://dx.doi.org/10.1107/S1600536814023150
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author Berger, Matthias
Auner, Norbert
Bolte, Michael
author_facet Berger, Matthias
Auner, Norbert
Bolte, Michael
author_sort Berger, Matthias
collection PubMed
description The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis­(2,6-diiso­propyl­phen­yl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in di­chloro­methane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8 (6)°; the dihedral angle between the benzene rings is 40.7 (2)°. The anion also lies on the mirror plane and both di­chloro­methane mol­ecules are disordered across the mirror plane over two equally occupied orientations. In the crystal, the cations are linked to the anions via C—H⋯Br hydrogen bonds.
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spelling pubmed-42572392014-12-05 Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate Berger, Matthias Auner, Norbert Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Data Reports The title solvated salt, C(29)H(41)N(2) (+)·Br(−)·2CH(2)Cl(2) was obtained from the reaction of the Arduengo-type carbene 1,3-bis­(2,6-diiso­propyl­phen­yl)-1,3-dihydro-4,5-dimethyl-2H-imidazol-2-ylidene with Si(2)Br(6) in di­chloro­methane. The complete cation is generated by a crystallographic mirror plane and the dihedral angle between the five-membered ring and the benzene ring is 89.8 (6)°; the dihedral angle between the benzene rings is 40.7 (2)°. The anion also lies on the mirror plane and both di­chloro­methane mol­ecules are disordered across the mirror plane over two equally occupied orientations. In the crystal, the cations are linked to the anions via C—H⋯Br hydrogen bonds. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257239/ /pubmed/25484824 http://dx.doi.org/10.1107/S1600536814023150 Text en © Berger et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Berger, Matthias
Auner, Norbert
Bolte, Michael
Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate
title Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate
title_full Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate
title_fullStr Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate
title_full_unstemmed Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate
title_short Crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1H-imid­azol-3-ium bromide di­chloro­methane disolvate
title_sort crystal structure of 1,3-bis­(2,6-diiso­propyl­phen­yl)-4,5-dimethyl-1h-imid­azol-3-ium bromide di­chloro­methane disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257239/
https://www.ncbi.nlm.nih.gov/pubmed/25484824
http://dx.doi.org/10.1107/S1600536814023150
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