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Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate

In the mol­ecular structure of the dinuclear title compound [η(5)-(C(5)(CH(3))(5))(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C(6)H(11))(3))]·C(6)H(6), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chlorido­borylene ligand (μ-BCl). The Pt(II) atom is additionally bound t...

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Autores principales: Braunschweig, Holger, Kramer, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257242/
https://www.ncbi.nlm.nih.gov/pubmed/25484763
http://dx.doi.org/10.1107/S1600536814023381
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author Braunschweig, Holger
Kramer, Thomas
author_facet Braunschweig, Holger
Kramer, Thomas
author_sort Braunschweig, Holger
collection PubMed
description In the mol­ecular structure of the dinuclear title compound [η(5)-(C(5)(CH(3))(5))(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C(6)H(11))(3))]·C(6)H(6), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chlorido­borylene ligand (μ-BCl). The Pt(II) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tri­cyclo­hexyl­phosphane ligand (PCy(3)) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the Pt(II) atom. The Fe(II) atom is bound to a penta­methyl­cyclo­penta­dienyl ligand [η(5)-C(5)(CH(3))(5)] and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent mol­ecule is incorporated into the crystal structure, positioned staggered relative to the penta­methyl­cyclo­penta­dienyl ligand at the Fe(II) atom, with a centroid–centroid separation of 3.630 (2) Å.
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spelling pubmed-42572422014-12-05 Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate Braunschweig, Holger Kramer, Thomas Acta Crystallogr Sect E Struct Rep Online Research Communications In the mol­ecular structure of the dinuclear title compound [η(5)-(C(5)(CH(3))(5))(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C(6)H(11))(3))]·C(6)H(6), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chlorido­borylene ligand (μ-BCl). The Pt(II) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tri­cyclo­hexyl­phosphane ligand (PCy(3)) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the Pt(II) atom. The Fe(II) atom is bound to a penta­methyl­cyclo­penta­dienyl ligand [η(5)-C(5)(CH(3))(5)] and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent mol­ecule is incorporated into the crystal structure, positioned staggered relative to the penta­methyl­cyclo­penta­dienyl ligand at the Fe(II) atom, with a centroid–centroid separation of 3.630 (2) Å. International Union of Crystallography 2014-10-29 /pmc/articles/PMC4257242/ /pubmed/25484763 http://dx.doi.org/10.1107/S1600536814023381 Text en © Braunschweig and Kramer 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Braunschweig, Holger
Kramer, Thomas
Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate
title Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate
title_full Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate
title_fullStr Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate
title_full_unstemmed Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate
title_short Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido­borylene-1:2κ(2) B:B-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κP)iron(II)platinum(II) benzene monosolvate
title_sort crystal structure of μ-1κc:2(η(2))-carbonyl-carbonyl-1κc-chlorido-2κcl-μ-chlorido­borylene-1:2κ(2) b:b-[1(η(5))-penta­methyl­cyclo­penta­dien­yl](tri­cyclo­hexyl­phosphane-2κp)iron(ii)platinum(ii) benzene monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257242/
https://www.ncbi.nlm.nih.gov/pubmed/25484763
http://dx.doi.org/10.1107/S1600536814023381
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AT kramerthomas crystalstructureofm1kc2ē2carbonylcarbonyl1kcchlorido2kclmchloridoborylene12k2bb1ē5pentamethylcyclopentadienyltricyclohexylphosphane2kpironiiplatinumiibenzenemonosolvate