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Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2) B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate
In the molecular structure of the dinuclear title compound [η(5)-(C(5)(CH(3))(5))(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C(6)H(11))(3))]·C(6)H(6), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chloridoborylene ligand (μ-BCl). The Pt(II) atom is additionally bound t...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257242/ https://www.ncbi.nlm.nih.gov/pubmed/25484763 http://dx.doi.org/10.1107/S1600536814023381 |
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author | Braunschweig, Holger Kramer, Thomas |
author_facet | Braunschweig, Holger Kramer, Thomas |
author_sort | Braunschweig, Holger |
collection | PubMed |
description | In the molecular structure of the dinuclear title compound [η(5)-(C(5)(CH(3))(5))(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C(6)H(11))(3))]·C(6)H(6), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chloridoborylene ligand (μ-BCl). The Pt(II) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tricyclohexylphosphane ligand (PCy(3)) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the Pt(II) atom. The Fe(II) atom is bound to a pentamethylcyclopentadienyl ligand [η(5)-C(5)(CH(3))(5)] and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent molecule is incorporated into the crystal structure, positioned staggered relative to the pentamethylcyclopentadienyl ligand at the Fe(II) atom, with a centroid–centroid separation of 3.630 (2) Å. |
format | Online Article Text |
id | pubmed-4257242 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572422014-12-05 Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2) B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate Braunschweig, Holger Kramer, Thomas Acta Crystallogr Sect E Struct Rep Online Research Communications In the molecular structure of the dinuclear title compound [η(5)-(C(5)(CH(3))(5))(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C(6)H(11))(3))]·C(6)H(6), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chloridoborylene ligand (μ-BCl). The Pt(II) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tricyclohexylphosphane ligand (PCy(3)) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the Pt(II) atom. The Fe(II) atom is bound to a pentamethylcyclopentadienyl ligand [η(5)-C(5)(CH(3))(5)] and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent molecule is incorporated into the crystal structure, positioned staggered relative to the pentamethylcyclopentadienyl ligand at the Fe(II) atom, with a centroid–centroid separation of 3.630 (2) Å. International Union of Crystallography 2014-10-29 /pmc/articles/PMC4257242/ /pubmed/25484763 http://dx.doi.org/10.1107/S1600536814023381 Text en © Braunschweig and Kramer 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Braunschweig, Holger Kramer, Thomas Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2) B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate |
title | Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2)
B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate |
title_full | Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2)
B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate |
title_fullStr | Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2)
B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate |
title_full_unstemmed | Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2)
B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate |
title_short | Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ(2)
B:B-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate |
title_sort | crystal structure of μ-1κc:2(η(2))-carbonyl-carbonyl-1κc-chlorido-2κcl-μ-chloridoborylene-1:2κ(2)
b:b-[1(η(5))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κp)iron(ii)platinum(ii) benzene monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257242/ https://www.ncbi.nlm.nih.gov/pubmed/25484763 http://dx.doi.org/10.1107/S1600536814023381 |
work_keys_str_mv | AT braunschweigholger crystalstructureofm1kc2ē2carbonylcarbonyl1kcchlorido2kclmchloridoborylene12k2bb1ē5pentamethylcyclopentadienyltricyclohexylphosphane2kpironiiplatinumiibenzenemonosolvate AT kramerthomas crystalstructureofm1kc2ē2carbonylcarbonyl1kcchlorido2kclmchloridoborylene12k2bb1ē5pentamethylcyclopentadienyltricyclohexylphosphane2kpironiiplatinumiibenzenemonosolvate |