Cargando…
Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4) O,N,O′,O′′}cadmium terephthalate
In the title salt, [Cd(C(6)H(15)NO(3))(2)](C(8)H(4)O(4)), the Cd(2+) cation is coordinated by six O atoms and two N atoms from two tetradentate 2-[bis(2-hydroxyethyl)amino]ethanol ligands, displaying a distorted square-antiprismatic coordination. The terephthalate dianion does not coordinate...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257248/ https://www.ncbi.nlm.nih.gov/pubmed/25484780 http://dx.doi.org/10.1107/S1600536814022375 |
| _version_ | 1782347710343413760 |
|---|---|
| author | Li, Ya-Ping Han, Li-Ying Ming, Julia Su, Guan-Fang |
| author_facet | Li, Ya-Ping Han, Li-Ying Ming, Julia Su, Guan-Fang |
| author_sort | Li, Ya-Ping |
| collection | PubMed |
| description | In the title salt, [Cd(C(6)H(15)NO(3))(2)](C(8)H(4)O(4)), the Cd(2+) cation is coordinated by six O atoms and two N atoms from two tetradentate 2-[bis(2-hydroxyethyl)amino]ethanol ligands, displaying a distorted square-antiprismatic coordination. The terephthalate dianion does not coordinate to the cation but is connected through O⋯H—O hydrogen bonds of medium strength to the complex cations, leading to a layered structure extending parallel to (100). |
| format | Online Article Text |
| id | pubmed-4257248 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-42572482014-12-05 Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4) O,N,O′,O′′}cadmium terephthalate Li, Ya-Ping Han, Li-Ying Ming, Julia Su, Guan-Fang Acta Crystallogr Sect E Struct Rep Online Data Reports In the title salt, [Cd(C(6)H(15)NO(3))(2)](C(8)H(4)O(4)), the Cd(2+) cation is coordinated by six O atoms and two N atoms from two tetradentate 2-[bis(2-hydroxyethyl)amino]ethanol ligands, displaying a distorted square-antiprismatic coordination. The terephthalate dianion does not coordinate to the cation but is connected through O⋯H—O hydrogen bonds of medium strength to the complex cations, leading to a layered structure extending parallel to (100). International Union of Crystallography 2014-10-18 /pmc/articles/PMC4257248/ /pubmed/25484780 http://dx.doi.org/10.1107/S1600536814022375 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Li, Ya-Ping Han, Li-Ying Ming, Julia Su, Guan-Fang Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4) O,N,O′,O′′}cadmium terephthalate |
| title | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4)
O,N,O′,O′′}cadmium terephthalate |
| title_full | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4)
O,N,O′,O′′}cadmium terephthalate |
| title_fullStr | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4)
O,N,O′,O′′}cadmium terephthalate |
| title_full_unstemmed | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4)
O,N,O′,O′′}cadmium terephthalate |
| title_short | Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4)
O,N,O′,O′′}cadmium terephthalate |
| title_sort | crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-κ(4)
o,n,o′,o′′}cadmium terephthalate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257248/ https://www.ncbi.nlm.nih.gov/pubmed/25484780 http://dx.doi.org/10.1107/S1600536814022375 |
| work_keys_str_mv | AT liyaping crystalstructureofbis2bis2hydroxyethylaminoethanolk4onoocadmiumterephthalate AT hanliying crystalstructureofbis2bis2hydroxyethylaminoethanolk4onoocadmiumterephthalate AT mingjulia crystalstructureofbis2bis2hydroxyethylaminoethanolk4onoocadmiumterephthalate AT suguanfang crystalstructureofbis2bis2hydroxyethylaminoethanolk4onoocadmiumterephthalate |