Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide

The title compound C(15)H(20)O(2)S, was identified as a product of di­allyl­ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of...

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Detalles Bibliográficos
Autores principales: Kotha, Sambasivarao, Gunta, Rama
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257250/
https://www.ncbi.nlm.nih.gov/pubmed/25484805
http://dx.doi.org/10.1107/S1600536814022053
Descripción
Sumario:The title compound C(15)H(20)O(2)S, was identified as a product of di­allyl­ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131). Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle.

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