Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide

The title compound C(15)H(20)O(2)S, was identified as a product of di­allyl­ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of...

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Detalles Bibliográficos
Autores principales: Kotha, Sambasivarao, Gunta, Rama
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257250/
https://www.ncbi.nlm.nih.gov/pubmed/25484805
http://dx.doi.org/10.1107/S1600536814022053
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author Kotha, Sambasivarao
Gunta, Rama
author_facet Kotha, Sambasivarao
Gunta, Rama
author_sort Kotha, Sambasivarao
collection PubMed
description The title compound C(15)H(20)O(2)S, was identified as a product of di­allyl­ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131). Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle.
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spelling pubmed-42572502014-12-05 Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide Kotha, Sambasivarao Gunta, Rama Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound C(15)H(20)O(2)S, was identified as a product of di­allyl­ation of the meso-isomer of the corresponding norbornene sulfone, and it is an achiral compound. The five-membered heterocycle adopts an envelope conformation with the S atom deviating by 0.795 (3) Å from the other atoms of the ring (r.m.s. deviation = 0.0131). Both allyl groups are anti-oriented relative to the S atom but their double bonds are directed in opposite directions relative to the plane of the heterocycle. International Union of Crystallography 2014-10-15 /pmc/articles/PMC4257250/ /pubmed/25484805 http://dx.doi.org/10.1107/S1600536814022053 Text en © Kotha and Gunta 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kotha, Sambasivarao
Gunta, Rama
Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
title Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
title_full Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
title_fullStr Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
title_full_unstemmed Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
title_short Crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
title_sort crystal structure of 1,3-diallyl-1,3,3a,4,7,7a-hexa­hydro-4,7-methano-2-benzo­thio­phene 2,2-dioxide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257250/
https://www.ncbi.nlm.nih.gov/pubmed/25484805
http://dx.doi.org/10.1107/S1600536814022053
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