Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one

In the title mol­ecule, C(17)H(12)N(4)OS, the thia­zole ring forms a dihedral angle of 10.8 (2)° with the phenyl ring and an angle of 3.1 (3)° with the indole ring system [which has a maximum deviation of 0.035 (2) Å]. The dihedral angle between the planes of the phenyl ring and the indole ring syst...

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Autores principales: Halasangi, Bhimashankar M., Badami, Prema S., Patil, Sangamesh A., Anil Kumar, G. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257251/
https://www.ncbi.nlm.nih.gov/pubmed/25484816
http://dx.doi.org/10.1107/S1600536814022715
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author Halasangi, Bhimashankar M.
Badami, Prema S.
Patil, Sangamesh A.
Anil Kumar, G. N.
author_facet Halasangi, Bhimashankar M.
Badami, Prema S.
Patil, Sangamesh A.
Anil Kumar, G. N.
author_sort Halasangi, Bhimashankar M.
collection PubMed
description In the title mol­ecule, C(17)H(12)N(4)OS, the thia­zole ring forms a dihedral angle of 10.8 (2)° with the phenyl ring and an angle of 3.1 (3)° with the indole ring system [which has a maximum deviation of 0.035 (2) Å]. The dihedral angle between the planes of the phenyl ring and the indole ring system is 11.5 (1)°. An intra­molecular N—H⋯O hydrogen bond is observed. In the crystal, pairs of N—H⋯O hydrogen bonds form inversion dimers with an R (2) (2)(8) graph-set motif.
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spelling pubmed-42572512014-12-05 Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one Halasangi, Bhimashankar M. Badami, Prema S. Patil, Sangamesh A. Anil Kumar, G. N. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title mol­ecule, C(17)H(12)N(4)OS, the thia­zole ring forms a dihedral angle of 10.8 (2)° with the phenyl ring and an angle of 3.1 (3)° with the indole ring system [which has a maximum deviation of 0.035 (2) Å]. The dihedral angle between the planes of the phenyl ring and the indole ring system is 11.5 (1)°. An intra­molecular N—H⋯O hydrogen bond is observed. In the crystal, pairs of N—H⋯O hydrogen bonds form inversion dimers with an R (2) (2)(8) graph-set motif. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257251/ /pubmed/25484816 http://dx.doi.org/10.1107/S1600536814022715 Text en © Halasangi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Halasangi, Bhimashankar M.
Badami, Prema S.
Patil, Sangamesh A.
Anil Kumar, G. N.
Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
title Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
title_full Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
title_fullStr Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
title_full_unstemmed Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
title_short Crystal structure of 3-[(E)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
title_sort crystal structure of 3-[(e)-2-(4-phenyl-1,3-thia­zol-2-yl)hydrazin-1-yl­idene]indolin-2-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257251/
https://www.ncbi.nlm.nih.gov/pubmed/25484816
http://dx.doi.org/10.1107/S1600536814022715
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