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Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3) O (1),O (1′):O (5)]
In the polymeric title compound, [Cd(C(7)H(4)O(6)S)(C(11)H(6)N(2)O)(H(2)O)(2)](n), the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hydroxy-5-sulfonatobenzoate (Hssal(2−)) ligands and by two N atoms from a 4,5-diazafluoren-9-one (Dafo) ligand in a distorted...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257252/ https://www.ncbi.nlm.nih.gov/pubmed/25484789 http://dx.doi.org/10.1107/S1600536814023472 |
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author | Wang, Chun-Xiang Li, Zhi-Feng |
author_facet | Wang, Chun-Xiang Li, Zhi-Feng |
author_sort | Wang, Chun-Xiang |
collection | PubMed |
description | In the polymeric title compound, [Cd(C(7)H(4)O(6)S)(C(11)H(6)N(2)O)(H(2)O)(2)](n), the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hydroxy-5-sulfonatobenzoate (Hssal(2−)) ligands and by two N atoms from a 4,5-diazafluoren-9-one (Dafo) ligand in a distorted pentagonal–bipyramidal geometry. The Cd(2+) atoms are monodentately coordinated by the sulfonate group of one Hssal(2−) ligand and bidentately coordinated by the carboxylate group of another Hssal(2−) ligand, generating zigzag chains running parallel to [010]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional architecture. |
format | Online Article Text |
id | pubmed-4257252 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572522014-12-05 Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3) O (1),O (1′):O (5)] Wang, Chun-Xiang Li, Zhi-Feng Acta Crystallogr Sect E Struct Rep Online Data Reports In the polymeric title compound, [Cd(C(7)H(4)O(6)S)(C(11)H(6)N(2)O)(H(2)O)(2)](n), the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hydroxy-5-sulfonatobenzoate (Hssal(2−)) ligands and by two N atoms from a 4,5-diazafluoren-9-one (Dafo) ligand in a distorted pentagonal–bipyramidal geometry. The Cd(2+) atoms are monodentately coordinated by the sulfonate group of one Hssal(2−) ligand and bidentately coordinated by the carboxylate group of another Hssal(2−) ligand, generating zigzag chains running parallel to [010]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional architecture. International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257252/ /pubmed/25484789 http://dx.doi.org/10.1107/S1600536814023472 Text en © Wang and Li 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Wang, Chun-Xiang Li, Zhi-Feng Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3) O (1),O (1′):O (5)] |
title | Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2)
N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3)
O
(1),O
(1′):O
(5)] |
title_full | Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2)
N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3)
O
(1),O
(1′):O
(5)] |
title_fullStr | Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2)
N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3)
O
(1),O
(1′):O
(5)] |
title_full_unstemmed | Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2)
N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3)
O
(1),O
(1′):O
(5)] |
title_short | Crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2)
N,N′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3)
O
(1),O
(1′):O
(5)] |
title_sort | crystal structure of catena-poly[[diaqua(4,5-diazafluoren-9-one-κ(2)
n,n′)cadmium]-μ-2-hydroxy-5-sulfonatobenzoato-κ(3)
o
(1),o
(1′):o
(5)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257252/ https://www.ncbi.nlm.nih.gov/pubmed/25484789 http://dx.doi.org/10.1107/S1600536814023472 |
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