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Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]

In the polymeric title compound, [Cd(C(7)H(4)O(6)S)(C(11)H(6)N(2)O)(H(2)O)(2)](n), the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hy­droxy-5-sulfonato­benzoate (Hssal(2−)) ligands and by two N atoms from a 4,5-di­aza­fluoren-9-one (Dafo) ligand in a distorted...

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Detalles Bibliográficos
Autores principales: Wang, Chun-Xiang, Li, Zhi-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257252/
https://www.ncbi.nlm.nih.gov/pubmed/25484789
http://dx.doi.org/10.1107/S1600536814023472
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author Wang, Chun-Xiang
Li, Zhi-Feng
author_facet Wang, Chun-Xiang
Li, Zhi-Feng
author_sort Wang, Chun-Xiang
collection PubMed
description In the polymeric title compound, [Cd(C(7)H(4)O(6)S)(C(11)H(6)N(2)O)(H(2)O)(2)](n), the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hy­droxy-5-sulfonato­benzoate (Hssal(2−)) ligands and by two N atoms from a 4,5-di­aza­fluoren-9-one (Dafo) ligand in a distorted penta­gonal–bipyramidal geometry. The Cd(2+) atoms are monodentately coordinated by the sulfonate group of one Hssal(2−) ligand and bidentately coordinated by the carboxyl­ate group of another Hssal(2−) ligand, generating zigzag chains running parallel to [010]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional architecture.
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spelling pubmed-42572522014-12-05 Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)] Wang, Chun-Xiang Li, Zhi-Feng Acta Crystallogr Sect E Struct Rep Online Data Reports In the polymeric title compound, [Cd(C(7)H(4)O(6)S)(C(11)H(6)N(2)O)(H(2)O)(2)](n), the Cd(2+) atom is seven-coordinated by two water O atoms, by three O atoms from two 2-hy­droxy-5-sulfonato­benzoate (Hssal(2−)) ligands and by two N atoms from a 4,5-di­aza­fluoren-9-one (Dafo) ligand in a distorted penta­gonal–bipyramidal geometry. The Cd(2+) atoms are monodentately coordinated by the sulfonate group of one Hssal(2−) ligand and bidentately coordinated by the carboxyl­ate group of another Hssal(2−) ligand, generating zigzag chains running parallel to [010]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional architecture. International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257252/ /pubmed/25484789 http://dx.doi.org/10.1107/S1600536814023472 Text en © Wang and Li 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Wang, Chun-Xiang
Li, Zhi-Feng
Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]
title Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]
title_full Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]
title_fullStr Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]
title_full_unstemmed Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]
title_short Crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) N,N′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) O (1),O (1′):O (5)]
title_sort crystal structure of catena-poly[[di­aqua(4,5-di­aza­fluoren-9-one-κ(2) n,n′)cadmium]-μ-2-hydroxy-5-sulfonato­benzoato-κ(3) o (1),o (1′):o (5)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257252/
https://www.ncbi.nlm.nih.gov/pubmed/25484789
http://dx.doi.org/10.1107/S1600536814023472
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