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Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone

In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)°...

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Detalles Bibliográficos
Autores principales: Sajitha, L. U., Sithambaresan, M., Jacob, Jomon P., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257253/
https://www.ncbi.nlm.nih.gov/pubmed/25484744
http://dx.doi.org/10.1107/S1600536814022338
Descripción
Sumario:In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring mol­ecules are connected via two inter­molecular hydrogen-bonding inter­actions (O—H⋯O and C—H⋯O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H⋯Cl inter­action [3.564 (2) Å] and three C—H⋯π inter­actions, with C⋯π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the mol­ecules, forming a three-dimensional supra­molecular architecture in the solid state.