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Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone

In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)°...

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Autores principales: Sajitha, L. U., Sithambaresan, M., Jacob, Jomon P., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257253/
https://www.ncbi.nlm.nih.gov/pubmed/25484744
http://dx.doi.org/10.1107/S1600536814022338
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author Sajitha, L. U.
Sithambaresan, M.
Jacob, Jomon P.
Kurup, M. R. Prathapachandra
author_facet Sajitha, L. U.
Sithambaresan, M.
Jacob, Jomon P.
Kurup, M. R. Prathapachandra
author_sort Sajitha, L. U.
collection PubMed
description In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring mol­ecules are connected via two inter­molecular hydrogen-bonding inter­actions (O—H⋯O and C—H⋯O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H⋯Cl inter­action [3.564 (2) Å] and three C—H⋯π inter­actions, with C⋯π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the mol­ecules, forming a three-dimensional supra­molecular architecture in the solid state.
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spelling pubmed-42572532014-12-05 Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone Sajitha, L. U. Sithambaresan, M. Jacob, Jomon P. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring mol­ecules are connected via two inter­molecular hydrogen-bonding inter­actions (O—H⋯O and C—H⋯O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H⋯Cl inter­action [3.564 (2) Å] and three C—H⋯π inter­actions, with C⋯π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the mol­ecules, forming a three-dimensional supra­molecular architecture in the solid state. International Union of Crystallography 2014-10-18 /pmc/articles/PMC4257253/ /pubmed/25484744 http://dx.doi.org/10.1107/S1600536814022338 Text en © Sajitha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sajitha, L. U.
Sithambaresan, M.
Jacob, Jomon P.
Kurup, M. R. Prathapachandra
Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
title Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
title_full Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
title_fullStr Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
title_full_unstemmed Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
title_short Crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
title_sort crystal structure of (4-chloro­phen­yl)[2-(10-hy­droxy­phenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257253/
https://www.ncbi.nlm.nih.gov/pubmed/25484744
http://dx.doi.org/10.1107/S1600536814022338
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