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Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone
In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)°...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257253/ https://www.ncbi.nlm.nih.gov/pubmed/25484744 http://dx.doi.org/10.1107/S1600536814022338 |
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author | Sajitha, L. U. Sithambaresan, M. Jacob, Jomon P. Kurup, M. R. Prathapachandra |
author_facet | Sajitha, L. U. Sithambaresan, M. Jacob, Jomon P. Kurup, M. R. Prathapachandra |
author_sort | Sajitha, L. U. |
collection | PubMed |
description | In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring molecules are connected via two intermolecular hydrogen-bonding interactions (O—H⋯O and C—H⋯O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H⋯Cl interaction [3.564 (2) Å] and three C—H⋯π interactions, with C⋯π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the molecules, forming a three-dimensional supramolecular architecture in the solid state. |
format | Online Article Text |
id | pubmed-4257253 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572532014-12-05 Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone Sajitha, L. U. Sithambaresan, M. Jacob, Jomon P. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(37)H(21)ClO(3), the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring molecules are connected via two intermolecular hydrogen-bonding interactions (O—H⋯O and C—H⋯O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H⋯Cl interaction [3.564 (2) Å] and three C—H⋯π interactions, with C⋯π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the molecules, forming a three-dimensional supramolecular architecture in the solid state. International Union of Crystallography 2014-10-18 /pmc/articles/PMC4257253/ /pubmed/25484744 http://dx.doi.org/10.1107/S1600536814022338 Text en © Sajitha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Sajitha, L. U. Sithambaresan, M. Jacob, Jomon P. Kurup, M. R. Prathapachandra Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
title | Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
title_full | Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
title_fullStr | Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
title_full_unstemmed | Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
title_short | Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
title_sort | crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257253/ https://www.ncbi.nlm.nih.gov/pubmed/25484744 http://dx.doi.org/10.1107/S1600536814022338 |
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