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Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
In the title compound, C(24)H(29)NO(3), the azabicycle contains two six-membered rings, viz. a cyclohexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257259/ https://www.ncbi.nlm.nih.gov/pubmed/25484811 http://dx.doi.org/10.1107/S1600536814022545 |
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author | Shreevidhyaa Suressh, V. Sathya, S. Akila, A. Ponnuswamy, S. Usha, G. |
author_facet | Shreevidhyaa Suressh, V. Sathya, S. Akila, A. Ponnuswamy, S. Usha, G. |
author_sort | Shreevidhyaa Suressh, V. |
collection | PubMed |
description | In the title compound, C(24)H(29)NO(3), the azabicycle contains two six-membered rings, viz. a cyclohexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another. The dihedral angle between the planes of the 4-methoxyphenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group. In the crystal, molecules are linked by C—H⋯π interactions forming chains along [10-1]. |
format | Online Article Text |
id | pubmed-4257259 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572592014-12-05 Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone Shreevidhyaa Suressh, V. Sathya, S. Akila, A. Ponnuswamy, S. Usha, G. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(24)H(29)NO(3), the azabicycle contains two six-membered rings, viz. a cyclohexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another. The dihedral angle between the planes of the 4-methoxyphenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group. In the crystal, molecules are linked by C—H⋯π interactions forming chains along [10-1]. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257259/ /pubmed/25484811 http://dx.doi.org/10.1107/S1600536814022545 Text en © Shreevidhyaa Suressh et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Shreevidhyaa Suressh, V. Sathya, S. Akila, A. Ponnuswamy, S. Usha, G. Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
title | Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
title_full | Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
title_fullStr | Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
title_full_unstemmed | Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
title_short | Crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
title_sort | crystal structure of 1-[2,4-bis(4-methoxyphenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257259/ https://www.ncbi.nlm.nih.gov/pubmed/25484811 http://dx.doi.org/10.1107/S1600536814022545 |
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