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Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone

In the title compound, C(24)H(29)NO(3), the aza­bicycle contains two six-membered rings, viz. a cyclo­hexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they a...

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Autores principales: Shreevidhyaa Suressh, V., Sathya, S., Akila, A., Ponnuswamy, S., Usha, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257259/
https://www.ncbi.nlm.nih.gov/pubmed/25484811
http://dx.doi.org/10.1107/S1600536814022545
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author Shreevidhyaa Suressh, V.
Sathya, S.
Akila, A.
Ponnuswamy, S.
Usha, G.
author_facet Shreevidhyaa Suressh, V.
Sathya, S.
Akila, A.
Ponnuswamy, S.
Usha, G.
author_sort Shreevidhyaa Suressh, V.
collection PubMed
description In the title compound, C(24)H(29)NO(3), the aza­bicycle contains two six-membered rings, viz. a cyclo­hexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another. The dihedral angle between the planes of the 4-meth­oxy­phenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group. In the crystal, mol­ecules are linked by C—H⋯π inter­actions forming chains along [10-1].
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spelling pubmed-42572592014-12-05 Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone Shreevidhyaa Suressh, V. Sathya, S. Akila, A. Ponnuswamy, S. Usha, G. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(24)H(29)NO(3), the aza­bicycle contains two six-membered rings, viz. a cyclo­hexane ring and a piperidine ring. The first adopts a chair conformation and the second a half-chair conformation. The dihedral angle between their mean planes is 86.21 (13)°, indicating that they are almost perpendicular to one another. The dihedral angle between the planes of the 4-meth­oxy­phenyl rings is 17.51 (13)°, and they make dihedral angles of 81.9 (3) and 81.3 (3)° with the ethan-1-one group. In the crystal, mol­ecules are linked by C—H⋯π inter­actions forming chains along [10-1]. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257259/ /pubmed/25484811 http://dx.doi.org/10.1107/S1600536814022545 Text en © Shreevidhyaa Suressh et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shreevidhyaa Suressh, V.
Sathya, S.
Akila, A.
Ponnuswamy, S.
Usha, G.
Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
title Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
title_full Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
title_fullStr Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
title_full_unstemmed Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
title_short Crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
title_sort crystal structure of 1-[2,4-bis(4-methoxy­phenyl)-3-azabicyclo[3.3.1]nonan-3-yl]ethanone
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257259/
https://www.ncbi.nlm.nih.gov/pubmed/25484811
http://dx.doi.org/10.1107/S1600536814022545
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