Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate

In the title compound, [Cu(ClO(4))(C(3)H(10)N(2))(2)(H(2)O)]ClO(4), the Cu(II) atom has a distorted octa­hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di­amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a dis...

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Detalles Bibliográficos
Autores principales: Govindaraj, J., Rajkumar, K., Ganeshraja, A. S., Anbalagan, K., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257260/
https://www.ncbi.nlm.nih.gov/pubmed/25484768
http://dx.doi.org/10.1107/S1600536814023496
Descripción
Sumario:In the title compound, [Cu(ClO(4))(C(3)H(10)N(2))(2)(H(2)O)]ClO(4), the Cu(II) atom has a distorted octa­hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di­amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming sheets lying parallel to (001).

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