Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate

In the title compound, [Cu(ClO(4))(C(3)H(10)N(2))(2)(H(2)O)]ClO(4), the Cu(II) atom has a distorted octa­hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di­amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a dis...

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Autores principales: Govindaraj, J., Rajkumar, K., Ganeshraja, A. S., Anbalagan, K., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257260/
https://www.ncbi.nlm.nih.gov/pubmed/25484768
http://dx.doi.org/10.1107/S1600536814023496
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author Govindaraj, J.
Rajkumar, K.
Ganeshraja, A. S.
Anbalagan, K.
SubbiahPandi, A.
author_facet Govindaraj, J.
Rajkumar, K.
Ganeshraja, A. S.
Anbalagan, K.
SubbiahPandi, A.
author_sort Govindaraj, J.
collection PubMed
description In the title compound, [Cu(ClO(4))(C(3)H(10)N(2))(2)(H(2)O)]ClO(4), the Cu(II) atom has a distorted octa­hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di­amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming sheets lying parallel to (001).
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spelling pubmed-42572602014-12-05 Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate Govindaraj, J. Rajkumar, K. Ganeshraja, A. S. Anbalagan, K. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Cu(ClO(4))(C(3)H(10)N(2))(2)(H(2)O)]ClO(4), the Cu(II) atom has a distorted octa­hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di­amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming sheets lying parallel to (001). International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257260/ /pubmed/25484768 http://dx.doi.org/10.1107/S1600536814023496 Text en © Govindaraj et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Govindaraj, J.
Rajkumar, K.
Ganeshraja, A. S.
Anbalagan, K.
SubbiahPandi, A.
Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate
title Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate
title_full Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate
title_fullStr Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate
title_full_unstemmed Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate
title_short Crystal structure of trans-aqua­(perchlorato-κO)bis­(propane-1,3-di­amine-κ(2) N,N′)copper(II) perchlorate
title_sort crystal structure of trans-aqua­(perchlorato-κo)bis­(propane-1,3-di­amine-κ(2) n,n′)copper(ii) perchlorate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257260/
https://www.ncbi.nlm.nih.gov/pubmed/25484768
http://dx.doi.org/10.1107/S1600536814023496
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