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Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3) O,N,O′}copper(II) terephthalate
The molecular components of the title salt, [Cu(C(4)H(11)NO(2))(2)](C(8)H(4)O(4)), are one Cu(II) cation O,N,O′-chelated by two tridentate 2-[(2-hydroxyethyl)amino]ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex Cu(II) cation is located abo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257266/ https://www.ncbi.nlm.nih.gov/pubmed/25484781 http://dx.doi.org/10.1107/S1600536814022272 |
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author | Li, Ya-Ping Sun, Dajun Ming, Julia Han, Liying Su, Guan-Fang |
author_facet | Li, Ya-Ping Sun, Dajun Ming, Julia Han, Liying Su, Guan-Fang |
author_sort | Li, Ya-Ping |
collection | PubMed |
description | The molecular components of the title salt, [Cu(C(4)H(11)NO(2))(2)](C(8)H(4)O(4)), are one Cu(II) cation O,N,O′-chelated by two tridentate 2-[(2-hydroxyethyl)amino]ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex Cu(II) cation is located about a centre of inversion and shows typical Jahn–Teller distortion, with two short Cu—O and two short Cu—N bonds in the equatorial plane and two long Cu—O bonds to the axial atoms. The cations are arranged in sheets parallel to (100), with the centrosymmetric terephthalate anions located between the sheets. Each anion is the acceptor of four O—H⋯O and two N—H⋯O hydrogen bonds, forming a three-dimensional network structure. |
format | Online Article Text |
id | pubmed-4257266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572662014-12-05 Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3) O,N,O′}copper(II) terephthalate Li, Ya-Ping Sun, Dajun Ming, Julia Han, Liying Su, Guan-Fang Acta Crystallogr Sect E Struct Rep Online Data Reports The molecular components of the title salt, [Cu(C(4)H(11)NO(2))(2)](C(8)H(4)O(4)), are one Cu(II) cation O,N,O′-chelated by two tridentate 2-[(2-hydroxyethyl)amino]ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex Cu(II) cation is located about a centre of inversion and shows typical Jahn–Teller distortion, with two short Cu—O and two short Cu—N bonds in the equatorial plane and two long Cu—O bonds to the axial atoms. The cations are arranged in sheets parallel to (100), with the centrosymmetric terephthalate anions located between the sheets. Each anion is the acceptor of four O—H⋯O and two N—H⋯O hydrogen bonds, forming a three-dimensional network structure. International Union of Crystallography 2014-10-18 /pmc/articles/PMC4257266/ /pubmed/25484781 http://dx.doi.org/10.1107/S1600536814022272 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Li, Ya-Ping Sun, Dajun Ming, Julia Han, Liying Su, Guan-Fang Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3) O,N,O′}copper(II) terephthalate |
title | Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}copper(II) terephthalate |
title_full | Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}copper(II) terephthalate |
title_fullStr | Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}copper(II) terephthalate |
title_full_unstemmed | Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}copper(II) terephthalate |
title_short | Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3)
O,N,O′}copper(II) terephthalate |
title_sort | crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ(3)
o,n,o′}copper(ii) terephthalate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257266/ https://www.ncbi.nlm.nih.gov/pubmed/25484781 http://dx.doi.org/10.1107/S1600536814022272 |
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