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Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate

The mol­ecular components of the title salt, [Cu(C(4)H(11)NO(2))(2)](C(8)H(4)O(4)), are one Cu(II) cation O,N,O′-chelated by two tridentate 2-[(2-hy­droxy­eth­yl)amino]­ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex Cu(II) cation is located abo...

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Autores principales: Li, Ya-Ping, Sun, Dajun, Ming, Julia, Han, Liying, Su, Guan-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257266/
https://www.ncbi.nlm.nih.gov/pubmed/25484781
http://dx.doi.org/10.1107/S1600536814022272
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author Li, Ya-Ping
Sun, Dajun
Ming, Julia
Han, Liying
Su, Guan-Fang
author_facet Li, Ya-Ping
Sun, Dajun
Ming, Julia
Han, Liying
Su, Guan-Fang
author_sort Li, Ya-Ping
collection PubMed
description The mol­ecular components of the title salt, [Cu(C(4)H(11)NO(2))(2)](C(8)H(4)O(4)), are one Cu(II) cation O,N,O′-chelated by two tridentate 2-[(2-hy­droxy­eth­yl)amino]­ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex Cu(II) cation is located about a centre of inversion and shows typical Jahn–Teller distortion, with two short Cu—O and two short Cu—N bonds in the equatorial plane and two long Cu—O bonds to the axial atoms. The cations are arranged in sheets parallel to (100), with the centrosymmetric terephthalate anions located between the sheets. Each anion is the acceptor of four O—H⋯O and two N—H⋯O hydrogen bonds, forming a three-dimensional network structure.
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spelling pubmed-42572662014-12-05 Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate Li, Ya-Ping Sun, Dajun Ming, Julia Han, Liying Su, Guan-Fang Acta Crystallogr Sect E Struct Rep Online Data Reports The mol­ecular components of the title salt, [Cu(C(4)H(11)NO(2))(2)](C(8)H(4)O(4)), are one Cu(II) cation O,N,O′-chelated by two tridentate 2-[(2-hy­droxy­eth­yl)amino]­ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex Cu(II) cation is located about a centre of inversion and shows typical Jahn–Teller distortion, with two short Cu—O and two short Cu—N bonds in the equatorial plane and two long Cu—O bonds to the axial atoms. The cations are arranged in sheets parallel to (100), with the centrosymmetric terephthalate anions located between the sheets. Each anion is the acceptor of four O—H⋯O and two N—H⋯O hydrogen bonds, forming a three-dimensional network structure. International Union of Crystallography 2014-10-18 /pmc/articles/PMC4257266/ /pubmed/25484781 http://dx.doi.org/10.1107/S1600536814022272 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Li, Ya-Ping
Sun, Dajun
Ming, Julia
Han, Liying
Su, Guan-Fang
Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate
title Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate
title_full Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate
title_fullStr Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate
title_full_unstemmed Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate
title_short Crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) O,N,O′}copper(II) terephthalate
title_sort crystal structure of bis­{2-[(2-hy­droxy­eth­yl)amino]­ethanol-κ(3) o,n,o′}copper(ii) terephthalate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257266/
https://www.ncbi.nlm.nih.gov/pubmed/25484781
http://dx.doi.org/10.1107/S1600536814022272
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