Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)

In the title compound, [Rh(C(6)H(5)N(4))Cl(2)(C(12)H(27)P)(2)], the Rh(III) ion is chelated by the singly deprotonated 2,2′-biimidazolate (Hbim(−)) ligand and coordinated by two chloride ions and two tri-n-butyl­phosphane ligands. The chloride ions and N atoms of the Hbim(−) ligand lie in a plane wh...

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Detalles Bibliográficos
Autores principales: Jin-Long, Ebihara, Masahiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257268/
https://www.ncbi.nlm.nih.gov/pubmed/25484746
http://dx.doi.org/10.1107/S1600536814022454
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author Jin-Long,
Ebihara, Masahiro
author_facet Jin-Long,
Ebihara, Masahiro
author_sort Jin-Long,
collection PubMed
description In the title compound, [Rh(C(6)H(5)N(4))Cl(2)(C(12)H(27)P)(2)], the Rh(III) ion is chelated by the singly deprotonated 2,2′-biimidazolate (Hbim(−)) ligand and coordinated by two chloride ions and two tri-n-butyl­phosphane ligands. The chloride ions and N atoms of the Hbim(−) ligand lie in a plane where the sum of X—Rh—X angles between cis sites is 360°. The phosphane ligands occupy the sites perpendicular to the plane, completing the overall distorted octahedral coordination sphere. The complex forms a self-complementary hydrogen-bonded dimer with the inversion-related complex through N—H⋯N hydrogen bonds.
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spelling pubmed-42572682014-12-05 Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III) Jin-Long, Ebihara, Masahiro Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Rh(C(6)H(5)N(4))Cl(2)(C(12)H(27)P)(2)], the Rh(III) ion is chelated by the singly deprotonated 2,2′-biimidazolate (Hbim(−)) ligand and coordinated by two chloride ions and two tri-n-butyl­phosphane ligands. The chloride ions and N atoms of the Hbim(−) ligand lie in a plane where the sum of X—Rh—X angles between cis sites is 360°. The phosphane ligands occupy the sites perpendicular to the plane, completing the overall distorted octahedral coordination sphere. The complex forms a self-complementary hydrogen-bonded dimer with the inversion-related complex through N—H⋯N hydrogen bonds. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257268/ /pubmed/25484746 http://dx.doi.org/10.1107/S1600536814022454 Text en © Jin-Long and Ebihara 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Jin-Long,
Ebihara, Masahiro
Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)
title Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)
title_full Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)
title_fullStr Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)
title_full_unstemmed Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)
title_short Crystal structure of di­chlorido­[2-(1H-imidazol-2-yl-κN (3))imidazolato-κN]bis­(tri-n-butyl­phosphane-κP)rhodium(III)
title_sort crystal structure of di­chlorido­[2-(1h-imidazol-2-yl-κn (3))imidazolato-κn]bis­(tri-n-butyl­phosphane-κp)rhodium(iii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257268/
https://www.ncbi.nlm.nih.gov/pubmed/25484746
http://dx.doi.org/10.1107/S1600536814022454
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