Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)

In the title compound, [Tm(C(6)H(5)Se)(3)(C(4)H(8)O)(3)], the Tm(III) atom lies on a threefold rotation axis and is coordinated by three phenyl­seleno­late ligands and three tetra­hydro­furan ligands leading to a distorted fac-octa­hedral coordination environment. The Tm—Se and Tm—O bond lengths are...

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Autores principales: Takaluoma, Esther M., Oilunkaniemi, Raija, Lehmann, Christian W., Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257276/
https://www.ncbi.nlm.nih.gov/pubmed/25484790
http://dx.doi.org/10.1107/S1600536814023733
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author Takaluoma, Esther M.
Oilunkaniemi, Raija
Lehmann, Christian W.
Laitinen, Risto S.
author_facet Takaluoma, Esther M.
Oilunkaniemi, Raija
Lehmann, Christian W.
Laitinen, Risto S.
author_sort Takaluoma, Esther M.
collection PubMed
description In the title compound, [Tm(C(6)H(5)Se)(3)(C(4)H(8)O)(3)], the Tm(III) atom lies on a threefold rotation axis and is coordinated by three phenyl­seleno­late ligands and three tetra­hydro­furan ligands leading to a distorted fac-octa­hedral coordination environment. The Tm—Se and Tm—O bond lengths are 2.7692 (17) and 2.345 (10) Å, respectively, and the bond angles are 91.32 (6)° for Se—Tm—Se, 92.6 (2) and 94.4 (2)° for Se—Tm—O, and 81.2 (3)° for O—Tm—O. In the crystal, the discrete complexes are linked by van der Waals inter­actions only. The crystal was refined as a non-merohedral twin (ratio = 0.65:0.35).
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spelling pubmed-42572762014-12-05 Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III) Takaluoma, Esther M. Oilunkaniemi, Raija Lehmann, Christian W. Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Tm(C(6)H(5)Se)(3)(C(4)H(8)O)(3)], the Tm(III) atom lies on a threefold rotation axis and is coordinated by three phenyl­seleno­late ligands and three tetra­hydro­furan ligands leading to a distorted fac-octa­hedral coordination environment. The Tm—Se and Tm—O bond lengths are 2.7692 (17) and 2.345 (10) Å, respectively, and the bond angles are 91.32 (6)° for Se—Tm—Se, 92.6 (2) and 94.4 (2)° for Se—Tm—O, and 81.2 (3)° for O—Tm—O. In the crystal, the discrete complexes are linked by van der Waals inter­actions only. The crystal was refined as a non-merohedral twin (ratio = 0.65:0.35). International Union of Crystallography 2014-10-31 /pmc/articles/PMC4257276/ /pubmed/25484790 http://dx.doi.org/10.1107/S1600536814023733 Text en © Takaluoma et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Takaluoma, Esther M.
Oilunkaniemi, Raija
Lehmann, Christian W.
Laitinen, Risto S.
Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)
title Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)
title_full Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)
title_fullStr Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)
title_full_unstemmed Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)
title_short Crystal structure of tris­(phenyl­seleno­lato-κSe)tris­(tetra­hydro­furan-κO)thulium(III)
title_sort crystal structure of tris­(phenyl­seleno­lato-κse)tris­(tetra­hydro­furan-κo)thulium(iii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257276/
https://www.ncbi.nlm.nih.gov/pubmed/25484790
http://dx.doi.org/10.1107/S1600536814023733
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