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Crystal structure of (E)-3-(5-bromo-2-hydroxyphenyl)acrylaldehyde
The title compound, C(9)H(7)BrO(2), displays a trans configuration with respect to the C=C double bond and is essentially planar [maximum deviation from the least-squares plane through all non-H atoms = 0.056 (4) Å]. The vinylaldehyde group adopts an extended conformation wih a C—C—C—C torsion angl...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257279/ https://www.ncbi.nlm.nih.gov/pubmed/25484839 http://dx.doi.org/10.1107/S1600536814023708 |
Sumario: | The title compound, C(9)H(7)BrO(2), displays a trans configuration with respect to the C=C double bond and is essentially planar [maximum deviation from the least-squares plane through all non-H atoms = 0.056 (4) Å]. The vinylaldehyde group adopts an extended conformation wih a C—C—C—C torsion angle of 179.7 (4)°. In the crystal, molecules are linked by classical O—H⋯O and weak C—H⋯O hydrogen bonds into a three-dimensional supramolecular network. |
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