Cargando…

Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate

In the title compound, C(27)H(21)N(3)O(6)·C(2)H(5)OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, mol­ecules are...

Descripción completa

Detalles Bibliográficos
Autores principales: Sun, Hong-Shun, Li, Yu-Long, Jiang, Hong, Xu, Ning, Xu, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257280/
https://www.ncbi.nlm.nih.gov/pubmed/25484748
http://dx.doi.org/10.1107/S1600536814022296
_version_ 1782347717737971712
author Sun, Hong-Shun
Li, Yu-Long
Jiang, Hong
Xu, Ning
Xu, Hong
author_facet Sun, Hong-Shun
Li, Yu-Long
Jiang, Hong
Xu, Ning
Xu, Hong
author_sort Sun, Hong-Shun
collection PubMed
description In the title compound, C(27)H(21)N(3)O(6)·C(2)H(5)OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds and weak C—H⋯π inter­actions into a three-dimensional supra­molecular architecture. A void of 33.0 (7) Å(3) is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O—H⋯O hydrogen bond, reinforcing the framework structure.
format Online
Article
Text
id pubmed-4257280
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-42572802014-12-05 Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate Sun, Hong-Shun Li, Yu-Long Jiang, Hong Xu, Ning Xu, Hong Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(27)H(21)N(3)O(6)·C(2)H(5)OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds and weak C—H⋯π inter­actions into a three-dimensional supra­molecular architecture. A void of 33.0 (7) Å(3) is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O—H⋯O hydrogen bond, reinforcing the framework structure. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257280/ /pubmed/25484748 http://dx.doi.org/10.1107/S1600536814022296 Text en © Sun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sun, Hong-Shun
Li, Yu-Long
Jiang, Hong
Xu, Ning
Xu, Hong
Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate
title Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate
title_full Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate
title_fullStr Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate
title_full_unstemmed Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate
title_short Crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) ethanol monosolvate
title_sort crystal structure of dimethyl 3,3′-[(3-nitro­phen­yl)methyl­ene]bis­(1h-indole-2-carboxyl­ate) ethanol monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257280/
https://www.ncbi.nlm.nih.gov/pubmed/25484748
http://dx.doi.org/10.1107/S1600536814022296
work_keys_str_mv AT sunhongshun crystalstructureofdimethyl333nitrophenylmethylenebis1hindole2carboxylateethanolmonosolvate
AT liyulong crystalstructureofdimethyl333nitrophenylmethylenebis1hindole2carboxylateethanolmonosolvate
AT jianghong crystalstructureofdimethyl333nitrophenylmethylenebis1hindole2carboxylateethanolmonosolvate
AT xuning crystalstructureofdimethyl333nitrophenylmethylenebis1hindole2carboxylateethanolmonosolvate
AT xuhong crystalstructureofdimethyl333nitrophenylmethylenebis1hindole2carboxylateethanolmonosolvate