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Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate
In the title compound, C(27)H(21)N(3)O(6)·C(2)H(5)OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, molecules are...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257280/ https://www.ncbi.nlm.nih.gov/pubmed/25484748 http://dx.doi.org/10.1107/S1600536814022296 |
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author | Sun, Hong-Shun Li, Yu-Long Jiang, Hong Xu, Ning Xu, Hong |
author_facet | Sun, Hong-Shun Li, Yu-Long Jiang, Hong Xu, Ning Xu, Hong |
author_sort | Sun, Hong-Shun |
collection | PubMed |
description | In the title compound, C(27)H(21)N(3)O(6)·C(2)H(5)OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds and weak C—H⋯π interactions into a three-dimensional supramolecular architecture. A void of 33.0 (7) Å(3) is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O—H⋯O hydrogen bond, reinforcing the framework structure. |
format | Online Article Text |
id | pubmed-4257280 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42572802014-12-05 Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate Sun, Hong-Shun Li, Yu-Long Jiang, Hong Xu, Ning Xu, Hong Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(27)H(21)N(3)O(6)·C(2)H(5)OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds and weak C—H⋯π interactions into a three-dimensional supramolecular architecture. A void of 33.0 (7) Å(3) is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O—H⋯O hydrogen bond, reinforcing the framework structure. International Union of Crystallography 2014-10-24 /pmc/articles/PMC4257280/ /pubmed/25484748 http://dx.doi.org/10.1107/S1600536814022296 Text en © Sun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Sun, Hong-Shun Li, Yu-Long Jiang, Hong Xu, Ning Xu, Hong Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate |
title | Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate |
title_full | Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate |
title_fullStr | Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate |
title_full_unstemmed | Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate |
title_short | Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate |
title_sort | crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1h-indole-2-carboxylate) ethanol monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257280/ https://www.ncbi.nlm.nih.gov/pubmed/25484748 http://dx.doi.org/10.1107/S1600536814022296 |
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